Et2Zn‐Mediated Gem‐Dicarboxylation of Cyclopropanols with CO2

Et2Zn‐Mediated Gem‐Dicarboxylation of Cyclopropanols with CO2

Abstract An unprecedented Et2Zn‐mediated gem‐dicarboxylation of C─C/C─H single bond of cyclopropanols with CO2 is disclosed, which provides a straightforward and efficient methodology for the synthesis of a variety of structurally diverse and useful malonic acids in moderate to excellent yields. The...

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Bibliographic Details
Main Authors: Hongjian Liu, Lei Shi, Xiaobin Tan, Bangxiong Kang, Gen Luo, Huanfeng Jiang, Chaorong Qi
Format: Article
Language:English
Published: Wiley 2024-03-01
Series:Advanced Science
Subjects:
carbon dioxide
cyclopropanols
dicarboxylation
malonic acids
Online Access:https://doi.org/10.1002/advs.202307633

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