Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
Hydrogen production from CO2 reforming of methane over 20wt%.Co/Nd2O3 has been investigated in a fixed bed stainless steel reactor. The 20wt%.Co/Nd2O3 catalyst was synthesized using wet impregnation method and characterized for thermal stability, textural property, crystallinity, morphology and nat...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)
2017-11-01
|
Series: | Journal of Applied Sciences and Environmental Management |
Subjects: | |
Online Access: | https://www.ajol.info/index.php/jasem/article/view/163047 |
Summary: | Hydrogen production from CO2 reforming of methane over 20wt%.Co/Nd2O3 has been investigated in a fixed bed stainless steel reactor. The 20wt%.Co/Nd2O3 catalyst was synthesized using wet impregnation method and characterized for thermal stability, textural property, crystallinity, morphology and nature of chemical bonds using techniques such as TGA, XRD, N2 adsorption-desorption, FESEM, EDX and FTIR. The CO2 reforming of methane was performed at feed ratio (CH4:CO2) between 0.1-1 and reaction temperature ranged 973-1023 K. The catalyst displayed good activity towards selectivity and yield of hydrogen as well as CO, a by product. The selectivity and yield of Hydrogen increases with feed ratio and reaction temperature. The 20wt%.Co/Nd2O3 catalyst displayed promising catalytic activity for hydrogen production with the highest yield and selectivity of 32.5% and 17.6% respectively.
Keywords: Cobalt; Greenhouse gases; Hydrogen; Reforming;; Neodymium (III)Oxide
|
---|---|
ISSN: | 2659-1502 2659-1499 |