Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst

Hydrogen production from CO2 reforming of methane over 20wt%.Co/Nd2O3 has been investigated in a fixed bed stainless steel reactor. The 20wt%.Co/Nd2O3 catalyst was synthesized using wet impregnation method and characterized for thermal stability, textural property, crystallinity, morphology and nat...

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Main Authors: V. Ayodele Bamidele, Herbert Offor Uchechukwu, Edokpayi Osariemen, Christopher, E. Akhabue, T. Akhihiero Ejiroghene, Chin Kui Cheng
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2017-11-01
Series:Journal of Applied Sciences and Environmental Management
Subjects:
Online Access:https://www.ajol.info/index.php/jasem/article/view/163047
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author V. Ayodele Bamidele
Herbert Offor Uchechukwu
Edokpayi Osariemen
Christopher, E. Akhabue
T. Akhihiero Ejiroghene
Chin Kui Cheng
author_facet V. Ayodele Bamidele
Herbert Offor Uchechukwu
Edokpayi Osariemen
Christopher, E. Akhabue
T. Akhihiero Ejiroghene
Chin Kui Cheng
author_sort V. Ayodele Bamidele
collection DOAJ
description Hydrogen production from CO2 reforming of methane over 20wt%.Co/Nd2O3 has been investigated in a fixed bed stainless steel reactor. The 20wt%.Co/Nd2O3 catalyst was synthesized using wet impregnation method and characterized for thermal stability, textural property, crystallinity, morphology and nature of chemical bonds using techniques such as TGA, XRD, N2 adsorption-desorption, FESEM, EDX and FTIR. The CO2 reforming of methane was performed at feed ratio (CH4:CO2) between 0.1-1 and reaction temperature ranged 973-1023 K. The catalyst displayed good activity towards selectivity and yield of hydrogen as well as CO, a by product. The selectivity and yield of Hydrogen increases with feed ratio and reaction temperature. The 20wt%.Co/Nd2O3 catalyst displayed promising catalytic activity for hydrogen production with the highest yield and selectivity of 32.5% and 17.6% respectively. Keywords: Cobalt; Greenhouse gases; Hydrogen; Reforming;; Neodymium (III)Oxide
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spelling doaj.art-248d1fe720a241b6ac83ccbb9ed79aa72024-04-02T19:55:59ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992017-11-0121610.4314/jasem.v21i6.9Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalystV. Ayodele BamideleHerbert Offor UchechukwuEdokpayi OsariemenChristopher, E. AkhabueT. Akhihiero EjirogheneChin Kui Cheng Hydrogen production from CO2 reforming of methane over 20wt%.Co/Nd2O3 has been investigated in a fixed bed stainless steel reactor. The 20wt%.Co/Nd2O3 catalyst was synthesized using wet impregnation method and characterized for thermal stability, textural property, crystallinity, morphology and nature of chemical bonds using techniques such as TGA, XRD, N2 adsorption-desorption, FESEM, EDX and FTIR. The CO2 reforming of methane was performed at feed ratio (CH4:CO2) between 0.1-1 and reaction temperature ranged 973-1023 K. The catalyst displayed good activity towards selectivity and yield of hydrogen as well as CO, a by product. The selectivity and yield of Hydrogen increases with feed ratio and reaction temperature. The 20wt%.Co/Nd2O3 catalyst displayed promising catalytic activity for hydrogen production with the highest yield and selectivity of 32.5% and 17.6% respectively. Keywords: Cobalt; Greenhouse gases; Hydrogen; Reforming;; Neodymium (III)Oxide https://www.ajol.info/index.php/jasem/article/view/163047CobaltGreenhouse gasesHydrogenReformingNeodymium (III)Oxide
spellingShingle V. Ayodele Bamidele
Herbert Offor Uchechukwu
Edokpayi Osariemen
Christopher, E. Akhabue
T. Akhihiero Ejiroghene
Chin Kui Cheng
Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
Journal of Applied Sciences and Environmental Management
Cobalt
Greenhouse gases
Hydrogen
Reforming
Neodymium (III)Oxide
title Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
title_full Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
title_fullStr Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
title_full_unstemmed Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
title_short Hydrogen Production From catalytic reforming of greenhouse gases (CO<sub>2</sub> and CH<sub>4</sub>) Over Neodymiun (III) oxide supported Cobalt catalyst
title_sort hydrogen production from catalytic reforming of greenhouse gases co sub 2 sub and ch sub 4 sub over neodymiun iii oxide supported cobalt catalyst
topic Cobalt
Greenhouse gases
Hydrogen
Reforming
Neodymium (III)Oxide
url https://www.ajol.info/index.php/jasem/article/view/163047
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