Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters
Understanding the relative strengths of metal–ligand and metal–metal interactions in ligated nanoclusters is key to tailoring their properties. Here, collision-induced dissociation of two series of atomically precise metal sulfide nanoclusters provides insight into the modulation of the core–ligand...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-10-01
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| Series: | Communications Chemistry |
| Online Access: | https://doi.org/10.1038/s42004-022-00750-z |
| _version_ | 1798028654637219840 |
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| author | Habib Gholipour-Ranjbar Deepika Puru Jena Julia Laskin |
| author_facet | Habib Gholipour-Ranjbar Deepika Puru Jena Julia Laskin |
| author_sort | Habib Gholipour-Ranjbar |
| collection | DOAJ |
| description | Understanding the relative strengths of metal–ligand and metal–metal interactions in ligated nanoclusters is key to tailoring their properties. Here, collision-induced dissociation of two series of atomically precise metal sulfide nanoclusters provides insight into the modulation of the core–ligand interactions of the atomically precise metal chalcogenide clusters. |
| first_indexed | 2024-04-11T19:11:31Z |
| format | Article |
| id | doaj.art-24e4a59aaffe4f2aa10aaddc78eee94d |
| institution | Directory Open Access Journal |
| issn | 2399-3669 |
| language | English |
| last_indexed | 2024-04-11T19:11:31Z |
| publishDate | 2022-10-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Communications Chemistry |
| spelling | doaj.art-24e4a59aaffe4f2aa10aaddc78eee94d2022-12-22T04:07:35ZengNature PortfolioCommunications Chemistry2399-36692022-10-01511810.1038/s42004-022-00750-zGas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclustersHabib Gholipour-Ranjbar0Deepika1Puru Jena2Julia Laskin3Department of Chemistry, Purdue UniversityDepartment of Physics, Virginia Commonwealth UniversityDepartment of Physics, Virginia Commonwealth UniversityDepartment of Chemistry, Purdue UniversityUnderstanding the relative strengths of metal–ligand and metal–metal interactions in ligated nanoclusters is key to tailoring their properties. Here, collision-induced dissociation of two series of atomically precise metal sulfide nanoclusters provides insight into the modulation of the core–ligand interactions of the atomically precise metal chalcogenide clusters.https://doi.org/10.1038/s42004-022-00750-z |
| spellingShingle | Habib Gholipour-Ranjbar Deepika Puru Jena Julia Laskin Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters Communications Chemistry |
| title | Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters |
| title_full | Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters |
| title_fullStr | Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters |
| title_full_unstemmed | Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters |
| title_short | Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6 + (M = Mn, Fe, Co, Ni) nanoclusters |
| title_sort | gas phase fragmentation of single heteroatom incorporated co5ms8 pet3 6 m mn fe co ni nanoclusters |
| url | https://doi.org/10.1038/s42004-022-00750-z |
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