Bis(2-amino-1,3-thiazole-κN3)diazidozinc
In the title complex, [Zn(N3)2(C3H4N2S)2], the ZnII atom is tetrahedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-aminothiazole ligands. Intramolecular N—H...N hydrogen bonds between the amino groups of both 2-aminothiazole ligands and the N...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810053766 |
| Summary: | In the title complex, [Zn(N3)2(C3H4N2S)2], the ZnII atom is tetrahedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-aminothiazole ligands. Intramolecular N—H...N hydrogen bonds between the amino groups of both 2-aminothiazole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Intermolecular N—H...N hydrogen bonds link the molecules into zigzag sheets in the ac plane. |
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| ISSN: | 1600-5368 |