Bis(2-amino-1,3-thiazole-κN3)diazidozinc

In the title complex, [Zn(N3)2(C3H4N2S)2], the ZnII atom is tetrahedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-aminothiazole ligands. Intramolecular N—H...N hydrogen bonds between the amino groups of both 2-aminothiazole ligands and the N...

Full description

Bibliographic Details
Main Authors: Seung Wook Suh, Chong-Hyeak Kim, Inn Hoe Kim
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810053766
_version_ 1819279872373030912
author Seung Wook Suh
Chong-Hyeak Kim
Inn Hoe Kim
author_facet Seung Wook Suh
Chong-Hyeak Kim
Inn Hoe Kim
author_sort Seung Wook Suh
collection DOAJ
description In the title complex, [Zn(N3)2(C3H4N2S)2], the ZnII atom is tetrahedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-aminothiazole ligands. Intramolecular N—H...N hydrogen bonds between the amino groups of both 2-aminothiazole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Intermolecular N—H...N hydrogen bonds link the molecules into zigzag sheets in the ac plane.
first_indexed 2024-12-24T00:34:48Z
format Article
id doaj.art-251c1e589eb9460a85200ccdb09a320f
institution Directory Open Access Journal
issn 1600-5368
language English
last_indexed 2024-12-24T00:34:48Z
publishDate 2011-02-01
publisher International Union of Crystallography
record_format Article
series Acta Crystallographica Section E
spelling doaj.art-251c1e589eb9460a85200ccdb09a320f2022-12-21T17:24:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m135m13610.1107/S1600536810053766Bis(2-amino-1,3-thiazole-κN3)diazidozincSeung Wook SuhChong-Hyeak KimInn Hoe KimIn the title complex, [Zn(N3)2(C3H4N2S)2], the ZnII atom is tetrahedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-aminothiazole ligands. Intramolecular N—H...N hydrogen bonds between the amino groups of both 2-aminothiazole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Intermolecular N—H...N hydrogen bonds link the molecules into zigzag sheets in the ac plane.http://scripts.iucr.org/cgi-bin/paper?S1600536810053766
spellingShingle Seung Wook Suh
Chong-Hyeak Kim
Inn Hoe Kim
Bis(2-amino-1,3-thiazole-κN3)diazidozinc
Acta Crystallographica Section E
title Bis(2-amino-1,3-thiazole-κN3)diazidozinc
title_full Bis(2-amino-1,3-thiazole-κN3)diazidozinc
title_fullStr Bis(2-amino-1,3-thiazole-κN3)diazidozinc
title_full_unstemmed Bis(2-amino-1,3-thiazole-κN3)diazidozinc
title_short Bis(2-amino-1,3-thiazole-κN3)diazidozinc
title_sort bis 2 amino 1 3 thiazole amp 954 n3 diazidozinc
url http://scripts.iucr.org/cgi-bin/paper?S1600536810053766
work_keys_str_mv AT seungwooksuh bis2amino13thiazoleamp954n3diazidozinc
AT chonghyeakkim bis2amino13thiazoleamp954n3diazidozinc
AT innhoekim bis2amino13thiazoleamp954n3diazidozinc