Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction

The aim of this research was to investigate the degradation of Penicillin G (PEN G) in synthesized wastewater via a Fenton-like reaction. Calcium dioxide (CaO2) was used as an oxidant in the Fenton-like reaction. Factors of the PEN G degradation study such as pH, FeSO4, CaO2, and reaction time were...

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Main Authors: Wiparat Nisapai, Athipong Paikamnam, Pongsert Sriprom, Sutasinee Neramittagapong, Somnuk Theerakulpisut, Chitsan Lin, Arthit Neramittagapong
Format: Article
Language:English
Published: Khon Kaen University 2022-09-01
Series:Engineering and Applied Science Research
Subjects:
Online Access:https://ph01.tci-thaijo.org/index.php/easr/article/view/247096/168588
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author Wiparat Nisapai
Athipong Paikamnam
Pongsert Sriprom
Sutasinee Neramittagapong
Somnuk Theerakulpisut
Chitsan Lin
Arthit Neramittagapong
author_facet Wiparat Nisapai
Athipong Paikamnam
Pongsert Sriprom
Sutasinee Neramittagapong
Somnuk Theerakulpisut
Chitsan Lin
Arthit Neramittagapong
author_sort Wiparat Nisapai
collection DOAJ
description The aim of this research was to investigate the degradation of Penicillin G (PEN G) in synthesized wastewater via a Fenton-like reaction. Calcium dioxide (CaO2) was used as an oxidant in the Fenton-like reaction. Factors of the PEN G degradation study such as pH, FeSO4, CaO2, and reaction time were determined using the Box-Behnken design (BBD). The experimental study was conducted in a 500 mL batch reactor, with 150 ppm initial concentration of PEN G. The results showed that PEN G degradation was optimal (38.67%) at pH 3, ferrous dosage of 0.08 g/L, CaO2 concentration of 1 g/L, and reaction time of 120 min. The degradation took place in the first 20 min. The reaction time was increased up to 120 min to achieve a pH of 8 in the test solution to meet the industrial effluent standard by the Ministry of Industry, Thailand. The kinetic study indicated second order and the pseudo first order reaction for the degradation in 0-20 min and 20-120 min, respectively. The research results indicated that pH, iron dosage, and CaO2 content-except reaction time-influenced PEN G degradation as predicted by the BBD. The degradation was substantially quick as well. Fenton-like reaction for a high concentration of PEN G should be used as pre-treatment.
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spelling doaj.art-251d052e7d044aa1888079b1aede3edd2022-12-22T03:35:26ZengKhon Kaen UniversityEngineering and Applied Science Research2539-61612539-62182022-09-01495622629Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reactionWiparat NisapaiAthipong PaikamnamPongsert SripromSutasinee NeramittagapongSomnuk TheerakulpisutChitsan Lin Arthit NeramittagapongThe aim of this research was to investigate the degradation of Penicillin G (PEN G) in synthesized wastewater via a Fenton-like reaction. Calcium dioxide (CaO2) was used as an oxidant in the Fenton-like reaction. Factors of the PEN G degradation study such as pH, FeSO4, CaO2, and reaction time were determined using the Box-Behnken design (BBD). The experimental study was conducted in a 500 mL batch reactor, with 150 ppm initial concentration of PEN G. The results showed that PEN G degradation was optimal (38.67%) at pH 3, ferrous dosage of 0.08 g/L, CaO2 concentration of 1 g/L, and reaction time of 120 min. The degradation took place in the first 20 min. The reaction time was increased up to 120 min to achieve a pH of 8 in the test solution to meet the industrial effluent standard by the Ministry of Industry, Thailand. The kinetic study indicated second order and the pseudo first order reaction for the degradation in 0-20 min and 20-120 min, respectively. The research results indicated that pH, iron dosage, and CaO2 content-except reaction time-influenced PEN G degradation as predicted by the BBD. The degradation was substantially quick as well. Fenton-like reaction for a high concentration of PEN G should be used as pre-treatment.https://ph01.tci-thaijo.org/index.php/easr/article/view/247096/168588antibiotics degradationadvance oxidationpenicillin gfenton-like reaction
spellingShingle Wiparat Nisapai
Athipong Paikamnam
Pongsert Sriprom
Sutasinee Neramittagapong
Somnuk Theerakulpisut
Chitsan Lin
Arthit Neramittagapong
Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
Engineering and Applied Science Research
antibiotics degradation
advance oxidation
penicillin g
fenton-like reaction
title Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
title_full Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
title_fullStr Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
title_full_unstemmed Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
title_short Degradation of Penicillin G contaminant in synthesized wastewater by Fenton-like reaction
title_sort degradation of penicillin g contaminant in synthesized wastewater by fenton like reaction
topic antibiotics degradation
advance oxidation
penicillin g
fenton-like reaction
url https://ph01.tci-thaijo.org/index.php/easr/article/view/247096/168588
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