Evidence for single metal two electron oxidative addition and reductive elimination at uranium
The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2017-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-01363-0 |
| _version_ | 1818341992089780224 |
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| author | Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle |
| author_facet | Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle |
| author_sort | Benedict M. Gardner |
| collection | DOAJ |
| description | The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry. |
| first_indexed | 2024-12-13T16:07:36Z |
| format | Article |
| id | doaj.art-2523f3b2e85c4ba3aef12ee29f04b159 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-13T16:07:36Z |
| publishDate | 2017-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-2523f3b2e85c4ba3aef12ee29f04b1592022-12-21T23:39:00ZengNature PortfolioNature Communications2041-17232017-12-018111010.1038/s41467-017-01363-0Evidence for single metal two electron oxidative addition and reductive elimination at uraniumBenedict M. Gardner0Christos E. Kefalidis1Erli Lu2Dipti Patel3Eric J. L. McInnes4Floriana Tuna5Ashley J. Wooles6Laurent Maron7Stephen T. Liddle8School of Chemistry, The University of ManchesterLPCNO, CNRS & INSA, Université Paul SabatierSchool of Chemistry, The University of ManchesterSchool of Chemistry, University of NottinghamEPSRC National UK EPR Facility, School of Chemistry and Photon Science Institute, The University of ManchesterEPSRC National UK EPR Facility, School of Chemistry and Photon Science Institute, The University of ManchesterSchool of Chemistry, The University of ManchesterLPCNO, CNRS & INSA, Université Paul SabatierSchool of Chemistry, The University of ManchesterThe reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.https://doi.org/10.1038/s41467-017-01363-0 |
| spellingShingle | Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle Evidence for single metal two electron oxidative addition and reductive elimination at uranium Nature Communications |
| title | Evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| title_full | Evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| title_fullStr | Evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| title_full_unstemmed | Evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| title_short | Evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| title_sort | evidence for single metal two electron oxidative addition and reductive elimination at uranium |
| url | https://doi.org/10.1038/s41467-017-01363-0 |
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