Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent
Dual functional graphene oxide (GO) microcapsules were fabricated through self-assembly in Pickering emulsions, carrying corrosion inhibitor benzotriazole (BTA) on the microcapsule shells and encapsulating a self-healing agent epoxy monomer. The formation of the GO microcapsules was assisted by the...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-09-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/14/19/4067 |
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| author | Jing Li Zhenglin Tao Jincan Cui Shuling Shen Hanxun Qiu |
| author_facet | Jing Li Zhenglin Tao Jincan Cui Shuling Shen Hanxun Qiu |
| author_sort | Jing Li |
| collection | DOAJ |
| description | Dual functional graphene oxide (GO) microcapsules were fabricated through self-assembly in Pickering emulsions, carrying corrosion inhibitor benzotriazole (BTA) on the microcapsule shells and encapsulating a self-healing agent epoxy monomer. The formation of the GO microcapsules was assisted by the interaction between BTA and GO, which provided robust encapsulation for the epoxy monomer. The loading capacity of BTA and epoxy monomer reached 90.5%. The addition of the GO microcapsules simultaneously promoted the corrosion protection and self-healing properties of the waterborne epoxy composite coatings. The healing efficiency of the composite coatings reached over 99.7% when the content of the microcapsules was 10 wt%. Meanwhile, the corrosion current density of the intact coatings was decreased for around 50 times. |
| first_indexed | 2024-03-09T21:15:40Z |
| format | Article |
| id | doaj.art-2529c863f1294f8c8c10a8cba77e5251 |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-09T21:15:40Z |
| publishDate | 2022-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-2529c863f1294f8c8c10a8cba77e52512023-11-23T21:33:42ZengMDPI AGPolymers2073-43602022-09-011419406710.3390/polym14194067Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing AgentJing Li0Zhenglin Tao1Jincan Cui2Shuling Shen3Hanxun Qiu4School of Materials and Chemistry, University of Shanghai for Science and Technology, No. 516 Jungong Road, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, No. 516 Jungong Road, Shanghai 200093, ChinaSchool of Mechanical Engineering, Nantong University, No. 9 Seyuan Road, Nantong 226019, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, No. 516 Jungong Road, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, No. 516 Jungong Road, Shanghai 200093, ChinaDual functional graphene oxide (GO) microcapsules were fabricated through self-assembly in Pickering emulsions, carrying corrosion inhibitor benzotriazole (BTA) on the microcapsule shells and encapsulating a self-healing agent epoxy monomer. The formation of the GO microcapsules was assisted by the interaction between BTA and GO, which provided robust encapsulation for the epoxy monomer. The loading capacity of BTA and epoxy monomer reached 90.5%. The addition of the GO microcapsules simultaneously promoted the corrosion protection and self-healing properties of the waterborne epoxy composite coatings. The healing efficiency of the composite coatings reached over 99.7% when the content of the microcapsules was 10 wt%. Meanwhile, the corrosion current density of the intact coatings was decreased for around 50 times.https://www.mdpi.com/2073-4360/14/19/4067composite coatingsmicrocapsulesgraphene oxidecorrosion protectionself-healing |
| spellingShingle | Jing Li Zhenglin Tao Jincan Cui Shuling Shen Hanxun Qiu Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent Polymers composite coatings microcapsules graphene oxide corrosion protection self-healing |
| title | Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent |
| title_full | Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent |
| title_fullStr | Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent |
| title_full_unstemmed | Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent |
| title_short | Facile Fabrication of Dual Functional Graphene Oxide Microcapsules Carrying Corrosion Inhibitor and Encapsulating Self-Healing Agent |
| title_sort | facile fabrication of dual functional graphene oxide microcapsules carrying corrosion inhibitor and encapsulating self healing agent |
| topic | composite coatings microcapsules graphene oxide corrosion protection self-healing |
| url | https://www.mdpi.com/2073-4360/14/19/4067 |
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