Crystal structure of 4-((1E)-1-{(2Z)-2-[4-(4-bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)phenol hemihydrate

In the title compound, C23H18BrN3OS·0.5H2O, the bromophenyl, phenyl and phenol rings make dihedral angles of 46.5 (1), 66.78 (8) and 15.4 (2)°, respectively, with the mean squares plane of the thiazolidene ring. In the crystal, the lattice water molecule is hydrogen bonded to the phenol group and ma...

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Bibliographic Details
Main Authors: Joel T. Mague, Mehmet Akkurt, Shaaban K. Mohamed, Alaa A. Hassan, Mustafa R. Albayati
Format: Article
Language:English
Published: International Union of Crystallography 2014-10-01
Series:Acta Crystallographica Section E
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814019473
Description
Summary:In the title compound, C23H18BrN3OS·0.5H2O, the bromophenyl, phenyl and phenol rings make dihedral angles of 46.5 (1), 66.78 (8) and 15.4 (2)°, respectively, with the mean squares plane of the thiazolidene ring. In the crystal, the lattice water molecule is hydrogen bonded to the phenol group and makes a weaker O—H...N connection to an inversion-related molecule, forming a ring while weak pairwise C—H...S interactions involving inversion-related molecules form a second ring. Both these motifs result in the formation of two-dimensional networks lying parallel to (10-1).
ISSN:1600-5368