Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative

Considering the considerable environmental impact resulting from basic chromium sulfate, the exploration of vegetable tanning materials as an eco-friendly alternative has gained substantial interest. This study endeavors to extract tannins from Pontederia crassipes using various solvents (water, ace...

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Main Authors: Md Asif Mustafa, Md Ashikur Rahaman Noyon, Md Elias Uddin, Rashedul Islam
Format: Article
Language:English
Published: Elsevier 2024-02-01
Series:Cleaner Engineering and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666790823001222
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author Md Asif Mustafa
Md Ashikur Rahaman Noyon
Md Elias Uddin
Rashedul Islam
author_facet Md Asif Mustafa
Md Ashikur Rahaman Noyon
Md Elias Uddin
Rashedul Islam
author_sort Md Asif Mustafa
collection DOAJ
description Considering the considerable environmental impact resulting from basic chromium sulfate, the exploration of vegetable tanning materials as an eco-friendly alternative has gained substantial interest. This study endeavors to extract tannins from Pontederia crassipes using various solvents (water, acetone, methanol, and ethanol) and evaluate their potential as a vegetable tanning agent for leather processing. Among the solvents, methanol exhibited the highest extraction efficiency at 26.34%. UV–Vis spectroscopy, FT-IR spectroscopy, and titrimetric analysis confirmed the presence of total tannins at 152.25 mg/g, which encompassed polyphenolic compounds such as epicatechin, catechin hydrate, and catechol. The antimicrobial behavior of the extracted tannin was confirmed by antimicrobial analysis. Notably, leather tanned with Pontederia crassipes tannin displayed an impressive shrinkage temperature of 83.31 °C, tensile strength 286.33 kg/cm2, and elongation 63.33%. This innovative tanning approach also yielded enhanced properties such as tensile strength, Bauman tear strength, stitch tear strength, tongue tear strength, and percentage of elongation, surpassing those of traditional vegetable-tanned leather. A closer look at the surface of the tanned leathers using Scanning electron microscopy (SEM) revealed compact fiber structures and uniform surface. Moreover, the Fourier-transform infrared spectroscopy (FTIR) analysis revealed clear functional groups within the Pontederia crassipes tanned leather, as evidenced by the broad peak observed. These results collectively imply that Pontederia crassipes tannin presents promise as an eco-friendly substitute for basic chromium sulfate and a novel reservoir of vegetable tannins for the leather sector.
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spelling doaj.art-25392778126b4099b6b60762c8ae04de2024-02-05T04:32:16ZengElsevierCleaner Engineering and Technology2666-79082024-02-0118100717Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternativeMd Asif Mustafa0Md Ashikur Rahaman Noyon1Md Elias Uddin2Rashedul Islam3Department of Leather Engineering, Faculty of Mechanical Engineering, Khulna University of Engineering & Technology, Khulna, 9203, BangladeshDepartment of Leather Engineering, Faculty of Mechanical Engineering, Khulna University of Engineering & Technology, Khulna, 9203, BangladeshCorresponding author.; Department of Leather Engineering, Faculty of Mechanical Engineering, Khulna University of Engineering & Technology, Khulna, 9203, BangladeshDepartment of Leather Engineering, Faculty of Mechanical Engineering, Khulna University of Engineering & Technology, Khulna, 9203, BangladeshConsidering the considerable environmental impact resulting from basic chromium sulfate, the exploration of vegetable tanning materials as an eco-friendly alternative has gained substantial interest. This study endeavors to extract tannins from Pontederia crassipes using various solvents (water, acetone, methanol, and ethanol) and evaluate their potential as a vegetable tanning agent for leather processing. Among the solvents, methanol exhibited the highest extraction efficiency at 26.34%. UV–Vis spectroscopy, FT-IR spectroscopy, and titrimetric analysis confirmed the presence of total tannins at 152.25 mg/g, which encompassed polyphenolic compounds such as epicatechin, catechin hydrate, and catechol. The antimicrobial behavior of the extracted tannin was confirmed by antimicrobial analysis. Notably, leather tanned with Pontederia crassipes tannin displayed an impressive shrinkage temperature of 83.31 °C, tensile strength 286.33 kg/cm2, and elongation 63.33%. This innovative tanning approach also yielded enhanced properties such as tensile strength, Bauman tear strength, stitch tear strength, tongue tear strength, and percentage of elongation, surpassing those of traditional vegetable-tanned leather. A closer look at the surface of the tanned leathers using Scanning electron microscopy (SEM) revealed compact fiber structures and uniform surface. Moreover, the Fourier-transform infrared spectroscopy (FTIR) analysis revealed clear functional groups within the Pontederia crassipes tanned leather, as evidenced by the broad peak observed. These results collectively imply that Pontederia crassipes tannin presents promise as an eco-friendly substitute for basic chromium sulfate and a novel reservoir of vegetable tannins for the leather sector.http://www.sciencedirect.com/science/article/pii/S2666790823001222Vegetable tanningPontederia crassipesEco-friendly leatherTannin extractionSustainable alternative
spellingShingle Md Asif Mustafa
Md Ashikur Rahaman Noyon
Md Elias Uddin
Rashedul Islam
Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
Cleaner Engineering and Technology
Vegetable tanning
Pontederia crassipes
Eco-friendly leather
Tannin extraction
Sustainable alternative
title Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
title_full Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
title_fullStr Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
title_full_unstemmed Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
title_short Sustainable leather tanning with Pontederia crassipes tannin: A promising eco-friendly alternative
title_sort sustainable leather tanning with pontederia crassipes tannin a promising eco friendly alternative
topic Vegetable tanning
Pontederia crassipes
Eco-friendly leather
Tannin extraction
Sustainable alternative
url http://www.sciencedirect.com/science/article/pii/S2666790823001222
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AT mdashikurrahamannoyon sustainableleathertanningwithpontederiacrassipestanninapromisingecofriendlyalternative
AT mdeliasuddin sustainableleathertanningwithpontederiacrassipestanninapromisingecofriendlyalternative
AT rashedulislam sustainableleathertanningwithpontederiacrassipestanninapromisingecofriendlyalternative