(2-Benzoyl-1-phenylethenolato-κ2O,O′)bis[2-(1-phenyl-1H-benzimidazol-2-yl)phenyl-κC1]iridium(III) dichloromethane disolvate

(2-Benzoyl-1-phenylethenolato-κ2O,O′)bis[2-(1-phenyl-1H-benzimidazol-2-yl)phenyl-κC1]iridium(III) dichloromethane disolvate

We present here synthesis and crystal structure of a neutral IrIII complex, [Ir(C19H13N2)2(C15H11O2)]·2CH2Cl2 or [Ir(C^N)2O^O]·2CH2Cl2, where C^N is 1,2-diphenyl-1H-benzimidazole and O^O is 2-benzoyl-1-phenylethenolate. The coordination sphere of the IrIII atom, located on a twofold rotation axis, i...

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Bibliographic Details
Main Authors: Stanislav I. Bezzubov, Vladimir D. Doljenko, Nikon M. Kurnosov, Irina S. Zharinova, Ilya V. Kovalenko, Yuri M. Kiselev
Format: Article
Language:English
Published: International Union of Crystallography 2016-12-01
Series:IUCrData
Subjects:
crystal structure
iridium complexes
dibenzoylmethane
benzimidazole
trans effect
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616019155

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http://scripts.iucr.org/cgi-bin/paper?S2414314616019155

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