Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants

The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption pr...

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Main Authors: Purenović Jelena M., Ranđelović Marjan S., Momčilović Milan Z., Purenović Milovan M., Stanković Novica J., Anđelković Ljiljana N.
Format: Article
Language:English
Published: Association of Chemical Engineers of Serbia 2017-01-01
Series:Hemijska Industrija
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0367-598X/2017/0367-598X1600040P.pdf
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author Purenović Jelena M.
Ranđelović Marjan S.
Momčilović Milan Z.
Purenović Milovan M.
Stanković Novica J.
Anđelković Ljiljana N.
author_facet Purenović Jelena M.
Ranđelović Marjan S.
Momčilović Milan Z.
Purenović Milovan M.
Stanković Novica J.
Anđelković Ljiljana N.
author_sort Purenović Jelena M.
collection DOAJ
description The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. III 45012]
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spelling doaj.art-254001971a9d4b6f9c643cd4eeb774ba2022-12-22T01:02:51ZengAssociation of Chemical Engineers of SerbiaHemijska Industrija0367-598X2217-74262017-01-0171429930610.2298/HEMIND160522040P0367-598X1600040PPhysicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutantsPurenović Jelena M.0Ranđelović Marjan S.1Momčilović Milan Z.2Purenović Milovan M.3Stanković Novica J.4Anđelković Ljiljana N.5Faculty of Technical Sciences, ČačakFaculty of Sciences and Mathematics, Department of Chemistry, NišVinča Institute of Nuclear Sciences, BelgradeFaculty of Sciences and Mathematics, Department of Chemistry, NišCollege of Textile, LeskovacFaculty of Technical Sciences, Kosovska MitrovicaThe physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. III 45012]http://www.doiserbia.nb.rs/img/doi/0367-598X/2017/0367-598X1600040P.pdfpeatphysicochemical modificationsurface groupsarsenichydrogen sulphideadsorption-sorption
spellingShingle Purenović Jelena M.
Ranđelović Marjan S.
Momčilović Milan Z.
Purenović Milovan M.
Stanković Novica J.
Anđelković Ljiljana N.
Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
Hemijska Industrija
peat
physicochemical modification
surface groups
arsenic
hydrogen sulphide
adsorption-sorption
title Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
title_full Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
title_fullStr Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
title_full_unstemmed Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
title_short Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
title_sort physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
topic peat
physicochemical modification
surface groups
arsenic
hydrogen sulphide
adsorption-sorption
url http://www.doiserbia.nb.rs/img/doi/0367-598X/2017/0367-598X1600040P.pdf
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