Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature
Abstract Organic reactions carried out in water under mild conditions are state‐of‐the‐art in terms of environmentally benign chemical processes. In this direction, plasmonic catalysis can aid in accomplishing such tasks. In the present work, cyclodextrin‐mediated AuPd bimetallic nanoparticles (NPs)...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2022-12-01
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| Series: | ChemistryOpen |
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| Online Access: | https://doi.org/10.1002/open.202200177 |
| _version_ | 1797954150228557824 |
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| author | Ana Paula Nazar de Souza Luiz Phelipe deSouza Tomaso Vitor Alexandre S. da Silva Gabriel Francisco S. da Silva Dr. Evelyn C. S. Santos Dr. Eustáquio deS. Baêta Prof. Dr. José Brant de Campos Prof. Dr. Nakédia M. F. Carvalho Prof. Dr. Luiz Fernando B. Malta Prof. Dr. Jaqueline D. Senra |
| author_facet | Ana Paula Nazar de Souza Luiz Phelipe deSouza Tomaso Vitor Alexandre S. da Silva Gabriel Francisco S. da Silva Dr. Evelyn C. S. Santos Dr. Eustáquio deS. Baêta Prof. Dr. José Brant de Campos Prof. Dr. Nakédia M. F. Carvalho Prof. Dr. Luiz Fernando B. Malta Prof. Dr. Jaqueline D. Senra |
| author_sort | Ana Paula Nazar de Souza |
| collection | DOAJ |
| description | Abstract Organic reactions carried out in water under mild conditions are state‐of‐the‐art in terms of environmentally benign chemical processes. In this direction, plasmonic catalysis can aid in accomplishing such tasks. In the present work, cyclodextrin‐mediated AuPd bimetallic nanoparticles (NPs) were applied in room‐temperature aqueous Suzuki‐Miyaura reactions aiming at preparing biaryl products based on fluorene, isatin, benzimidazole and resorcinol, with yields of 77 % up to 95 %. AuPd NPs were revealed to be a physical mixture of Au and Pd particles circa 20 and 2 nm, respectively, through X‐ray diffraction, dynamic light scattering, UV‐Vis spectroscopy and transmission electron microscopy analyses. |
| first_indexed | 2024-04-10T23:14:07Z |
| format | Article |
| id | doaj.art-254195ee2c1e403c97f6a921c953de2d |
| institution | Directory Open Access Journal |
| issn | 2191-1363 |
| language | English |
| last_indexed | 2024-04-10T23:14:07Z |
| publishDate | 2022-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemistryOpen |
| spelling | doaj.art-254195ee2c1e403c97f6a921c953de2d2023-01-13T01:50:53ZengWiley-VCHChemistryOpen2191-13632022-12-011112n/an/a10.1002/open.202200177Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room TemperatureAna Paula Nazar de Souza0Luiz Phelipe deSouza Tomaso1Vitor Alexandre S. da Silva2Gabriel Francisco S. da Silva3Dr. Evelyn C. S. Santos4Dr. Eustáquio deS. Baêta5Prof. Dr. José Brant de Campos6Prof. Dr. Nakédia M. F. Carvalho7Prof. Dr. Luiz Fernando B. Malta8Prof. Dr. Jaqueline D. Senra9Instituto de Química Universidade do Estado do Rio de Janeiro Rio de Janeiro 20550-900 BrazilInstituto de Química Universidade Federal do Rio de Janeiro Rio de Janeiro 21941-909 BrazilInstituto de Química Universidade Federal do Rio de Janeiro Rio de Janeiro 21941-909 BrazilInstituto de Química Universidade do Estado do Rio de Janeiro Rio de Janeiro 20550-900 BrazilInstituto de Química Universidade Federal do Rio de Janeiro Rio de Janeiro 21941-909 BrazilDepartamento de Engenharia Mecânica Universidade do Estado do Rio de Janeiro 20940-200 BrazilDepartamento de Engenharia Mecânica Universidade do Estado do Rio de Janeiro 20940-200 BrazilInstituto de Química Universidade do Estado do Rio de Janeiro Rio de Janeiro 20550-900 BrazilInstituto de Química Universidade Federal do Rio de Janeiro Rio de Janeiro 21941-909 BrazilInstituto de Química Universidade do Estado do Rio de Janeiro Rio de Janeiro 20550-900 BrazilAbstract Organic reactions carried out in water under mild conditions are state‐of‐the‐art in terms of environmentally benign chemical processes. In this direction, plasmonic catalysis can aid in accomplishing such tasks. In the present work, cyclodextrin‐mediated AuPd bimetallic nanoparticles (NPs) were applied in room‐temperature aqueous Suzuki‐Miyaura reactions aiming at preparing biaryl products based on fluorene, isatin, benzimidazole and resorcinol, with yields of 77 % up to 95 %. AuPd NPs were revealed to be a physical mixture of Au and Pd particles circa 20 and 2 nm, respectively, through X‐ray diffraction, dynamic light scattering, UV‐Vis spectroscopy and transmission electron microscopy analyses.https://doi.org/10.1002/open.202200177waterbiarylAu nanoparticlesPd nanoparticlesplasmonic catalysis |
| spellingShingle | Ana Paula Nazar de Souza Luiz Phelipe deSouza Tomaso Vitor Alexandre S. da Silva Gabriel Francisco S. da Silva Dr. Evelyn C. S. Santos Dr. Eustáquio deS. Baêta Prof. Dr. José Brant de Campos Prof. Dr. Nakédia M. F. Carvalho Prof. Dr. Luiz Fernando B. Malta Prof. Dr. Jaqueline D. Senra Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature ChemistryOpen water biaryl Au nanoparticles Pd nanoparticles plasmonic catalysis |
| title | Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature |
| title_full | Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature |
| title_fullStr | Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature |
| title_full_unstemmed | Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature |
| title_short | Mild and Rapid Light‐Driven Suzuki‐Miyaura Reactions Catalyzed by AuPd Nanoparticles in Water at Room Temperature |
| title_sort | mild and rapid light driven suzuki miyaura reactions catalyzed by aupd nanoparticles in water at room temperature |
| topic | water biaryl Au nanoparticles Pd nanoparticles plasmonic catalysis |
| url | https://doi.org/10.1002/open.202200177 |
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