Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
In this work, the mediated reduction of Fe(CN)63- and Fe3+ in poly(o-aminophenol) coated electrodes is analyzed by means of a diagnosis diagram based on the features of the steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the ex...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Association of Physical Chemists (IAPC)
2018-08-01
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| Series: | Journal of Electrochemical Science and Engineering |
| Subjects: | |
| Online Access: | http://pub.iapchem.org/ojs/index.php/JESE/article/view/582 |
| _version_ | 1818144903049248768 |
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| author | Gabriel Ybarra Carlos Moina María Inés Florit Dionisio Posadas |
| author_facet | Gabriel Ybarra Carlos Moina María Inés Florit Dionisio Posadas |
| author_sort | Gabriel Ybarra |
| collection | DOAJ |
| description | In this work, the mediated reduction of Fe(CN)63- and Fe3+ in poly(o-aminophenol) coated electrodes is analyzed by means of a diagnosis diagram based on the features of the steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamic parameters with a minimum amount of experimental measurements. |
| first_indexed | 2024-12-11T11:54:57Z |
| format | Article |
| id | doaj.art-255f4f8a0fe24d6a9c762833c468ccb6 |
| institution | Directory Open Access Journal |
| issn | 1847-9286 |
| language | English |
| last_indexed | 2024-12-11T11:54:57Z |
| publishDate | 2018-08-01 |
| publisher | International Association of Physical Chemists (IAPC) |
| record_format | Article |
| series | Journal of Electrochemical Science and Engineering |
| spelling | doaj.art-255f4f8a0fe24d6a9c762833c468ccb62022-12-22T01:08:14ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862018-08-018410.5599/jese.582333Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curvesGabriel Ybarra0Carlos Moina1María Inés Florit2Dionisio Posadas3Instituto Nacional de Tecnología Industrial, Av. Gral. Paz 5445, CC 157, WAB1650B San MartínInstituto Nacional de Tecnología Industrial, Av. Gral. Paz 5445, CC 157, WAB1650B San MartínInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de LaInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La PlataIn this work, the mediated reduction of Fe(CN)63- and Fe3+ in poly(o-aminophenol) coated electrodes is analyzed by means of a diagnosis diagram based on the features of the steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamic parameters with a minimum amount of experimental measurements.http://pub.iapchem.org/ojs/index.php/JESE/article/view/582Current rectificationdiagnostic diagramselectroactive polymersredox polymers |
| spellingShingle | Gabriel Ybarra Carlos Moina María Inés Florit Dionisio Posadas Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves Journal of Electrochemical Science and Engineering Current rectification diagnostic diagrams electroactive polymers redox polymers |
| title | Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves |
| title_full | Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves |
| title_fullStr | Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves |
| title_full_unstemmed | Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves |
| title_short | Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves |
| title_sort | redox mediation at poly o aminophenol coated electrodes mechanistic diagnosis from steady state polarization curves |
| topic | Current rectification diagnostic diagrams electroactive polymers redox polymers |
| url | http://pub.iapchem.org/ojs/index.php/JESE/article/view/582 |
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