Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe
Chalcogenide semiconductors and semimetals are a fertile class of efficient thermoelectric materials, which, in most cases, exhibit very low lattice thermal conductivity κ_{ph} despite lacking a complex crystal structure such as the tetragonal binary compound InTe. Our measurements of κ_{ph}(T) in s...
| Main Authors: | , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Physical Society
2020-12-01
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| Series: | Physical Review Research |
| Online Access: | http://doi.org/10.1103/PhysRevResearch.2.043371 |
| _version_ | 1827285902412480512 |
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| author | Shantanu Misra Céline Barreteau Jean-Claude Crivello Valentina M. Giordano John-Paul Castellan Yvan Sidis Petr Levinský Jiří Hejtmánek Bernard Malaman Anne Dauscher Bertrand Lenoir Christophe Candolfi Stéphane Pailhès |
| author_facet | Shantanu Misra Céline Barreteau Jean-Claude Crivello Valentina M. Giordano John-Paul Castellan Yvan Sidis Petr Levinský Jiří Hejtmánek Bernard Malaman Anne Dauscher Bertrand Lenoir Christophe Candolfi Stéphane Pailhès |
| author_sort | Shantanu Misra |
| collection | DOAJ |
| description | Chalcogenide semiconductors and semimetals are a fertile class of efficient thermoelectric materials, which, in most cases, exhibit very low lattice thermal conductivity κ_{ph} despite lacking a complex crystal structure such as the tetragonal binary compound InTe. Our measurements of κ_{ph}(T) in single-crystalline InTe along the c axis show that κ_{ph} exhibits a smooth temperature dependence upon cooling to about 50 K, the temperature below which a strong rise typical for dielectric compounds is observed. Using a combination of first-principles calculations, inelastic neutron scattering (INS), and low-temperature specific heat and transport properties measurements on single-crystalline InTe, we show that the phonon spectrum exhibits well-defined acoustic modes, the energy dispersions of which are constrained to low energies due to distributions of dispersionless, optical modes, which are responsible for a broad double peak structure in the low-temperature specific heat. The latter are assigned to the dynamics of In^{+} cations in tunnels formed by edge-sharing (In^{3+}Te_{4}^{2−})^{−} tetrahedra chains, the atomic thermal displacement parameters of which, probed as a function of temperature by means of single-crystal x-ray diffraction, suggest the existence of a complex energy potential. Indeed, the In^{+}-weighted optical modes are not observed by INS, which is ascribed to the anharmonic broadening of their energy profiles. While the low κ_{ph} value of 1.2Wm^{−1}K^{−1} at 300 K originates from the limited energy range available for acoustic phonons, we show that the underlying mechanism is specific to InTe and argue that it is likely related to the presence of local disorder induced by the In^{+} site occupancy. |
| first_indexed | 2024-04-24T10:21:21Z |
| format | Article |
| id | doaj.art-25638d998b21433fb744ecbfae5a2a13 |
| institution | Directory Open Access Journal |
| issn | 2643-1564 |
| language | English |
| last_indexed | 2024-04-24T10:21:21Z |
| publishDate | 2020-12-01 |
| publisher | American Physical Society |
| record_format | Article |
| series | Physical Review Research |
| spelling | doaj.art-25638d998b21433fb744ecbfae5a2a132024-04-12T17:05:10ZengAmerican Physical SocietyPhysical Review Research2643-15642020-12-012404337110.1103/PhysRevResearch.2.043371Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTeShantanu MisraCéline BarreteauJean-Claude CrivelloValentina M. GiordanoJohn-Paul CastellanYvan SidisPetr LevinskýJiří HejtmánekBernard MalamanAnne DauscherBertrand LenoirChristophe CandolfiStéphane PailhèsChalcogenide semiconductors and semimetals are a fertile class of efficient thermoelectric materials, which, in most cases, exhibit very low lattice thermal conductivity κ_{ph} despite lacking a complex crystal structure such as the tetragonal binary compound InTe. Our measurements of κ_{ph}(T) in single-crystalline InTe along the c axis show that κ_{ph} exhibits a smooth temperature dependence upon cooling to about 50 K, the temperature below which a strong rise typical for dielectric compounds is observed. Using a combination of first-principles calculations, inelastic neutron scattering (INS), and low-temperature specific heat and transport properties measurements on single-crystalline InTe, we show that the phonon spectrum exhibits well-defined acoustic modes, the energy dispersions of which are constrained to low energies due to distributions of dispersionless, optical modes, which are responsible for a broad double peak structure in the low-temperature specific heat. The latter are assigned to the dynamics of In^{+} cations in tunnels formed by edge-sharing (In^{3+}Te_{4}^{2−})^{−} tetrahedra chains, the atomic thermal displacement parameters of which, probed as a function of temperature by means of single-crystal x-ray diffraction, suggest the existence of a complex energy potential. Indeed, the In^{+}-weighted optical modes are not observed by INS, which is ascribed to the anharmonic broadening of their energy profiles. While the low κ_{ph} value of 1.2Wm^{−1}K^{−1} at 300 K originates from the limited energy range available for acoustic phonons, we show that the underlying mechanism is specific to InTe and argue that it is likely related to the presence of local disorder induced by the In^{+} site occupancy.http://doi.org/10.1103/PhysRevResearch.2.043371 |
| spellingShingle | Shantanu Misra Céline Barreteau Jean-Claude Crivello Valentina M. Giordano John-Paul Castellan Yvan Sidis Petr Levinský Jiří Hejtmánek Bernard Malaman Anne Dauscher Bertrand Lenoir Christophe Candolfi Stéphane Pailhès Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe Physical Review Research |
| title | Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe |
| title_full | Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe |
| title_fullStr | Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe |
| title_full_unstemmed | Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe |
| title_short | Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe |
| title_sort | reduced phase space of heat carrying acoustic phonons in single crystalline inte |
| url | http://doi.org/10.1103/PhysRevResearch.2.043371 |
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