Solid Electrolytes for Lithium Batteries
The use of solid electrolytes to produce an all-solid-state lithium battery is regarded as one promising alterative for improved safety. In this work, the researchers synthesized cubic garnet-type ceramic electrolyte Li6.75La3Zr1.75Ta0.25O12 (LLZTO) via the coprecipitation method. For the characteri...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Universitas Indonesia
2018-12-01
|
| Series: | International Journal of Technology |
| Subjects: | |
| Online Access: | http://ijtech.eng.ui.ac.id/article/view/2502 |
| _version_ | 1797968398706016256 |
|---|---|
| author | Xingxing Zhang Jeffrey W Fergus |
| author_facet | Xingxing Zhang Jeffrey W Fergus |
| author_sort | Xingxing Zhang |
| collection | DOAJ |
| description | The use of solid electrolytes to produce an all-solid-state lithium battery is regarded as one promising alterative for improved safety. In this work, the researchers synthesized cubic garnet-type ceramic electrolyte Li6.75La3Zr1.75Ta0.25O12 (LLZTO) via the coprecipitation method. For the characterization, the phase content was determined using X-ray diffraction (XRD), morphology was obtained by using a scanning electron microscope (SEM), and conductivity was measured by AC impedance spectroscopy using a frequency response analyzer. The results showed that the room temperature total conductivity and activation energies of LLZTO were 7.2×10-6 S/cm and 0.31-0.46 eV, respectively. Composite electrolytes were prepared by mixing LLZTO with a ceramic (Li1.4Al0.4Ti1.6(PO4)) (NASICON) or a polymer polyethylene oxide (PEO) with LiClO4 salt. The LLZTO-NASICON composite showed a higher total conductivity of 1.2×10-5 S/cm and activation energies of 0.23-0.58 eV. Compared to LLZTO, the LLZTO-PEO(LiClO4) composite showed a similar room temperature total conductivity of 1.2×10-6 S/cm, but a higher activation energy of 0.59-0.85 eV. |
| first_indexed | 2024-04-11T02:46:16Z |
| format | Article |
| id | doaj.art-256bcce102da41ed995d33cad041a6b8 |
| institution | Directory Open Access Journal |
| issn | 2086-9614 2087-2100 |
| language | English |
| last_indexed | 2024-04-11T02:46:16Z |
| publishDate | 2018-12-01 |
| publisher | Universitas Indonesia |
| record_format | Article |
| series | International Journal of Technology |
| spelling | doaj.art-256bcce102da41ed995d33cad041a6b82023-01-02T17:51:44ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002018-12-01961178118610.14716/ijtech.v9i6.25022502Solid Electrolytes for Lithium BatteriesXingxing Zhang0Jeffrey W Fergus1Materials Research and Education Center, Auburn University, Auburn, Alabama 36849, USAMaterials Research and Education Center, Auburn University, Auburn, Alabama 36849, USAThe use of solid electrolytes to produce an all-solid-state lithium battery is regarded as one promising alterative for improved safety. In this work, the researchers synthesized cubic garnet-type ceramic electrolyte Li6.75La3Zr1.75Ta0.25O12 (LLZTO) via the coprecipitation method. For the characterization, the phase content was determined using X-ray diffraction (XRD), morphology was obtained by using a scanning electron microscope (SEM), and conductivity was measured by AC impedance spectroscopy using a frequency response analyzer. The results showed that the room temperature total conductivity and activation energies of LLZTO were 7.2×10-6 S/cm and 0.31-0.46 eV, respectively. Composite electrolytes were prepared by mixing LLZTO with a ceramic (Li1.4Al0.4Ti1.6(PO4)) (NASICON) or a polymer polyethylene oxide (PEO) with LiClO4 salt. The LLZTO-NASICON composite showed a higher total conductivity of 1.2×10-5 S/cm and activation energies of 0.23-0.58 eV. Compared to LLZTO, the LLZTO-PEO(LiClO4) composite showed a similar room temperature total conductivity of 1.2×10-6 S/cm, but a higher activation energy of 0.59-0.85 eV.http://ijtech.eng.ui.ac.id/article/view/2502GarnetSolid composite electrolyteSolid electrolyte |
| spellingShingle | Xingxing Zhang Jeffrey W Fergus Solid Electrolytes for Lithium Batteries International Journal of Technology Garnet Solid composite electrolyte Solid electrolyte |
| title | Solid Electrolytes for Lithium Batteries |
| title_full | Solid Electrolytes for Lithium Batteries |
| title_fullStr | Solid Electrolytes for Lithium Batteries |
| title_full_unstemmed | Solid Electrolytes for Lithium Batteries |
| title_short | Solid Electrolytes for Lithium Batteries |
| title_sort | solid electrolytes for lithium batteries |
| topic | Garnet Solid composite electrolyte Solid electrolyte |
| url | http://ijtech.eng.ui.ac.id/article/view/2502 |
| work_keys_str_mv | AT xingxingzhang solidelectrolytesforlithiumbatteries AT jeffreywfergus solidelectrolytesforlithiumbatteries |