β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens

A novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of...

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Main Authors: Zhimin Liu, Qingqing Zhou, Dan Wang, Yunli Duan, Xuehua Zhang, Yi Yang, Zhigang Xu
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/23/18/10753
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author Zhimin Liu
Qingqing Zhou
Dan Wang
Yunli Duan
Xuehua Zhang
Yi Yang
Zhigang Xu
author_facet Zhimin Liu
Qingqing Zhou
Dan Wang
Yunli Duan
Xuehua Zhang
Yi Yang
Zhigang Xu
author_sort Zhimin Liu
collection DOAJ
description A novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of the derived β-cyclodextrin, which is beneficial to significantly improve the adsorption ability of fiber for parabens. Upon combination with HPLC, a specific and sensitive recognition method was developed with a low limit of detection (0.003–0.02 µg/L, S/N = 3) for parabens analysis in environmental water. This method has a good linearity (R > 0.9994) in the linear range of 0.01–200 µg/L. The proposed SMIP fiber array with high-throughput adsorption capacity has great potential in monitoring water pollution, which also provides a reliable reference for the analysis of more categories of pharmaceutical and personal care product pollutants.
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spelling doaj.art-25b61b93686c4460adf924cf1ac526f12023-11-23T16:47:27ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672022-09-0123181075310.3390/ijms231810753β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of ParabensZhimin Liu0Qingqing Zhou1Dan Wang2Yunli Duan3Xuehua Zhang4Yi Yang5Zhigang Xu6Department of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaA novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of the derived β-cyclodextrin, which is beneficial to significantly improve the adsorption ability of fiber for parabens. Upon combination with HPLC, a specific and sensitive recognition method was developed with a low limit of detection (0.003–0.02 µg/L, S/N = 3) for parabens analysis in environmental water. This method has a good linearity (R > 0.9994) in the linear range of 0.01–200 µg/L. The proposed SMIP fiber array with high-throughput adsorption capacity has great potential in monitoring water pollution, which also provides a reliable reference for the analysis of more categories of pharmaceutical and personal care product pollutants.https://www.mdpi.com/1422-0067/23/18/10753β-cyclodextrinsupramoleculemolecular imprintingfiber array extractionparabens
spellingShingle Zhimin Liu
Qingqing Zhou
Dan Wang
Yunli Duan
Xuehua Zhang
Yi Yang
Zhigang Xu
β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
International Journal of Molecular Sciences
β-cyclodextrin
supramolecule
molecular imprinting
fiber array extraction
parabens
title β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
title_full β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
title_fullStr β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
title_full_unstemmed β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
title_short β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
title_sort β cyclodextrin based supramolecular imprinted fiber array for highly selective detection of parabens
topic β-cyclodextrin
supramolecule
molecular imprinting
fiber array extraction
parabens
url https://www.mdpi.com/1422-0067/23/18/10753
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