β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens
A novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of...
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MDPI AG
2022-09-01
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Online Access: | https://www.mdpi.com/1422-0067/23/18/10753 |
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author | Zhimin Liu Qingqing Zhou Dan Wang Yunli Duan Xuehua Zhang Yi Yang Zhigang Xu |
author_facet | Zhimin Liu Qingqing Zhou Dan Wang Yunli Duan Xuehua Zhang Yi Yang Zhigang Xu |
author_sort | Zhimin Liu |
collection | DOAJ |
description | A novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of the derived β-cyclodextrin, which is beneficial to significantly improve the adsorption ability of fiber for parabens. Upon combination with HPLC, a specific and sensitive recognition method was developed with a low limit of detection (0.003–0.02 µg/L, S/N = 3) for parabens analysis in environmental water. This method has a good linearity (R > 0.9994) in the linear range of 0.01–200 µg/L. The proposed SMIP fiber array with high-throughput adsorption capacity has great potential in monitoring water pollution, which also provides a reliable reference for the analysis of more categories of pharmaceutical and personal care product pollutants. |
first_indexed | 2024-03-09T23:43:34Z |
format | Article |
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issn | 1661-6596 1422-0067 |
language | English |
last_indexed | 2024-03-09T23:43:34Z |
publishDate | 2022-09-01 |
publisher | MDPI AG |
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series | International Journal of Molecular Sciences |
spelling | doaj.art-25b61b93686c4460adf924cf1ac526f12023-11-23T16:47:27ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672022-09-0123181075310.3390/ijms231810753β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of ParabensZhimin Liu0Qingqing Zhou1Dan Wang2Yunli Duan3Xuehua Zhang4Yi Yang5Zhigang Xu6Department of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaDepartment of Chemistry, Faculty of Science, Kunming University of Science and Technology, Kunming 650500, ChinaA novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of the derived β-cyclodextrin, which is beneficial to significantly improve the adsorption ability of fiber for parabens. Upon combination with HPLC, a specific and sensitive recognition method was developed with a low limit of detection (0.003–0.02 µg/L, S/N = 3) for parabens analysis in environmental water. This method has a good linearity (R > 0.9994) in the linear range of 0.01–200 µg/L. The proposed SMIP fiber array with high-throughput adsorption capacity has great potential in monitoring water pollution, which also provides a reliable reference for the analysis of more categories of pharmaceutical and personal care product pollutants.https://www.mdpi.com/1422-0067/23/18/10753β-cyclodextrinsupramoleculemolecular imprintingfiber array extractionparabens |
spellingShingle | Zhimin Liu Qingqing Zhou Dan Wang Yunli Duan Xuehua Zhang Yi Yang Zhigang Xu β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens International Journal of Molecular Sciences β-cyclodextrin supramolecule molecular imprinting fiber array extraction parabens |
title | β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens |
title_full | β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens |
title_fullStr | β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens |
title_full_unstemmed | β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens |
title_short | β-Cyclodextrin-Based Supramolecular Imprinted Fiber Array for Highly Selective Detection of Parabens |
title_sort | β cyclodextrin based supramolecular imprinted fiber array for highly selective detection of parabens |
topic | β-cyclodextrin supramolecule molecular imprinting fiber array extraction parabens |
url | https://www.mdpi.com/1422-0067/23/18/10753 |
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