Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement

Selective laser sintering (SLS) of copper components manufactured via powder metallurgy is widely studied due to minimal material wastage. However, copper has poor optical absorption when exposed to infrared (IR) lasers, such as in laser-based additive manufacturing or laser surface processing. To a...

Full description

Bibliographic Details
Main Authors: Hasan Ayub, Lehar Asip Khan, Eanna McCarthy, Inam Ul Ahad, Karsten Fleischer, Dermot Brabazon
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/12/1984
_version_ 1797380036146233344
author Hasan Ayub
Lehar Asip Khan
Eanna McCarthy
Inam Ul Ahad
Karsten Fleischer
Dermot Brabazon
author_facet Hasan Ayub
Lehar Asip Khan
Eanna McCarthy
Inam Ul Ahad
Karsten Fleischer
Dermot Brabazon
author_sort Hasan Ayub
collection DOAJ
description Selective laser sintering (SLS) of copper components manufactured via powder metallurgy is widely studied due to minimal material wastage. However, copper has poor optical absorption when exposed to infrared (IR) lasers, such as in laser-based additive manufacturing or laser surface processing. To address this issue, an innovative approach to enhance the optical absorption of copper powders during infrared laser sintering is presented in this study. Carbon nanotubes (CNTs) have several unique properties, including their high surface area, plasmonic response, excellent conductivity, and optical absorption properties. CNTs were mixed with copper powders at different weight percentages using an acoustic method. The resulting Cu-CNT compositions were fabricated into pellets. The Box-Behnken Design of Experiments methodology was used to optimize the IR laser processing conditions for sintering. Spectroscopic analysis was conducted to evaluate the reflection and thermal absorption of the IR wavelengths by the Cu-CNT composites. Density and hardness measurements were taken for the laser-sintered Cu-CNT pellets. The coating of copper powders with CNTs demonstrated enhanced optical absorption and correspondingly reduced reflection. Due to the enhanced optical absorption, increased control and sensitivity of the laser sintering process was achieved, which enabled improvement in the mechanical properties of strength, hardness, and density, while also enabling control over the composite thermal expansion coefficient. A maximum average hardness of 66.5 HV was observed. Indentation test results of the samples revealed maximum tangential and radial stresses of 0.148 MPa and 0.058 Mpa, respectively.
first_indexed 2024-03-08T20:31:40Z
format Article
id doaj.art-25e15629e0b9413c99ec51d74887a0ba
institution Directory Open Access Journal
issn 2075-4701
language English
last_indexed 2024-03-08T20:31:40Z
publishDate 2023-12-01
publisher MDPI AG
record_format Article
series Metals
spelling doaj.art-25e15629e0b9413c99ec51d74887a0ba2023-12-22T14:24:44ZengMDPI AGMetals2075-47012023-12-011312198410.3390/met13121984Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process ImprovementHasan Ayub0Lehar Asip Khan1Eanna McCarthy2Inam Ul Ahad3Karsten Fleischer4Dermot Brabazon5I-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandI-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandI-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandI-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandI-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandI-Form Advanced Manufacturing Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City University, D09 V209 Dublin, IrelandSelective laser sintering (SLS) of copper components manufactured via powder metallurgy is widely studied due to minimal material wastage. However, copper has poor optical absorption when exposed to infrared (IR) lasers, such as in laser-based additive manufacturing or laser surface processing. To address this issue, an innovative approach to enhance the optical absorption of copper powders during infrared laser sintering is presented in this study. Carbon nanotubes (CNTs) have several unique properties, including their high surface area, plasmonic response, excellent conductivity, and optical absorption properties. CNTs were mixed with copper powders at different weight percentages using an acoustic method. The resulting Cu-CNT compositions were fabricated into pellets. The Box-Behnken Design of Experiments methodology was used to optimize the IR laser processing conditions for sintering. Spectroscopic analysis was conducted to evaluate the reflection and thermal absorption of the IR wavelengths by the Cu-CNT composites. Density and hardness measurements were taken for the laser-sintered Cu-CNT pellets. The coating of copper powders with CNTs demonstrated enhanced optical absorption and correspondingly reduced reflection. Due to the enhanced optical absorption, increased control and sensitivity of the laser sintering process was achieved, which enabled improvement in the mechanical properties of strength, hardness, and density, while also enabling control over the composite thermal expansion coefficient. A maximum average hardness of 66.5 HV was observed. Indentation test results of the samples revealed maximum tangential and radial stresses of 0.148 MPa and 0.058 Mpa, respectively.https://www.mdpi.com/2075-4701/13/12/1984copper-CNT compositecarbon nanotubelaser sinteringthermal-electrical expansionadditive manufacturing
spellingShingle Hasan Ayub
Lehar Asip Khan
Eanna McCarthy
Inam Ul Ahad
Karsten Fleischer
Dermot Brabazon
Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
Metals
copper-CNT composite
carbon nanotube
laser sintering
thermal-electrical expansion
additive manufacturing
title Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
title_full Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
title_fullStr Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
title_full_unstemmed Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
title_short Investigation on Optical Absorption and Reflection of Carbon Nanotubes Mixed Copper Composites for Laser Sintering Process Improvement
title_sort investigation on optical absorption and reflection of carbon nanotubes mixed copper composites for laser sintering process improvement
topic copper-CNT composite
carbon nanotube
laser sintering
thermal-electrical expansion
additive manufacturing
url https://www.mdpi.com/2075-4701/13/12/1984
work_keys_str_mv AT hasanayub investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement
AT leharasipkhan investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement
AT eannamccarthy investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement
AT inamulahad investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement
AT karstenfleischer investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement
AT dermotbrabazon investigationonopticalabsorptionandreflectionofcarbonnanotubesmixedcoppercompositesforlasersinteringprocessimprovement