Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique

The present study discusses the thermoluminescence (TL) characteristics of monoclinic barium titanate (BaTi5O11) which is chemically prepared using the sol–gel technique. The crystallinity is confirmed by X-ray diffraction, and the oxidation state of each element, morphology, and particle size of th...

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Main Authors: Manar Mostafa, Mohamed F. El-Shahat, Mohamed El-Kinawy, Nabil El-Faramawy, Moritz Riede, Ghada Bassioni
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535223007098
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author Manar Mostafa
Mohamed F. El-Shahat
Mohamed El-Kinawy
Nabil El-Faramawy
Moritz Riede
Ghada Bassioni
author_facet Manar Mostafa
Mohamed F. El-Shahat
Mohamed El-Kinawy
Nabil El-Faramawy
Moritz Riede
Ghada Bassioni
author_sort Manar Mostafa
collection DOAJ
description The present study discusses the thermoluminescence (TL) characteristics of monoclinic barium titanate (BaTi5O11) which is chemically prepared using the sol–gel technique. The crystallinity is confirmed by X-ray diffraction, and the oxidation state of each element, morphology, and particle size of the prepared powder are chemically probed by different spectroscopic tools including X-ray Photoelectron Spectroscopy and Energy dispersive X-Ray spectroscopy. The sample is irradiated by a beta (β)-source with different applied doses in the range of 1.1––385 Gy. The kinetic parameters which correspond to the charge carrier traps were determined. The analysis methods indicated that the TL glow curve of BaTi5O11 consists of 6 overlapped peaks corresponding to 6 electron traps. The values for the trap depth are found to be in the range 0.94–1.40 eV and the TL glow peaks are located between 380.4 and 560.5 K. The study confirms the potential of BaTi5O11 for β-dosimetry.
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spelling doaj.art-25e34827fb4b4e7da119fe0d3a2ab9672023-10-18T04:30:42ZengElsevierArabian Journal of Chemistry1878-53522023-11-011611105247Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence techniqueManar Mostafa0Mohamed F. El-Shahat1Mohamed El-Kinawy2Nabil El-Faramawy3Moritz Riede4Ghada Bassioni5Chemistry Division, Faculty of Engineering, Ain Shams University, P.O.Box 11517, Cairo, EgyptDepartment of Chemistry, Faculty of Science, Ain Shams University, P.O.Box 11566, Cairo, EgyptDepartment of Physics, Faculty of Science, Ain Shams University, P.O.Box 11566, Cairo, EgyptDepartment of Physics, Faculty of Science, Ain Shams University, P.O.Box 11566, Cairo, EgyptDepartment of Physics, University of Oxford, Oxford OX1 3PU, UKChemistry Division, Faculty of Engineering, Ain Shams University, P.O.Box 11517, Cairo, Egypt; Chemistry Department, Technical University Munich, 85748, Garching b. Muenchen, Germany; Corresponding author.The present study discusses the thermoluminescence (TL) characteristics of monoclinic barium titanate (BaTi5O11) which is chemically prepared using the sol–gel technique. The crystallinity is confirmed by X-ray diffraction, and the oxidation state of each element, morphology, and particle size of the prepared powder are chemically probed by different spectroscopic tools including X-ray Photoelectron Spectroscopy and Energy dispersive X-Ray spectroscopy. The sample is irradiated by a beta (β)-source with different applied doses in the range of 1.1––385 Gy. The kinetic parameters which correspond to the charge carrier traps were determined. The analysis methods indicated that the TL glow curve of BaTi5O11 consists of 6 overlapped peaks corresponding to 6 electron traps. The values for the trap depth are found to be in the range 0.94–1.40 eV and the TL glow peaks are located between 380.4 and 560.5 K. The study confirms the potential of BaTi5O11 for β-dosimetry.http://www.sciencedirect.com/science/article/pii/S1878535223007098BaTi5O11Sol-gelThermoluminescenceDosimetry
spellingShingle Manar Mostafa
Mohamed F. El-Shahat
Mohamed El-Kinawy
Nabil El-Faramawy
Moritz Riede
Ghada Bassioni
Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
Arabian Journal of Chemistry
BaTi5O11
Sol-gel
Thermoluminescence
Dosimetry
title Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
title_full Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
title_fullStr Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
title_full_unstemmed Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
title_short Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique
title_sort studying the kinetic parameters of bati5o11 by using the thermoluminescence technique
topic BaTi5O11
Sol-gel
Thermoluminescence
Dosimetry
url http://www.sciencedirect.com/science/article/pii/S1878535223007098
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AT nabilelfaramawy studyingthekineticparametersofbati5o11byusingthethermoluminescencetechnique
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