Complexes of 1,8-bis(hydrazidomethylsulfo­nyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II)

1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4...

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Bibliographic Details
Main Authors: V.V. Neklyudov, G.A. Boos, M.M. Shulaeva, O.A. Lodochnikova, G.A. Chmutowa, E.P. Bulavina, R.R. Amirov
Format: Article
Language:English
Published: Kazan Federal University 2020-03-01
Series:Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki
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Online Access:https://kpfu.ru/uz-eng-ns-2020-1-3.html
Description
Summary:1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4.5–5.0 and with copper(II), they form cationic mono- and binuclear complexes. Preparatively isolated copper complexes with each of the two compounds have different compositions, which also differ from the composition of complexes in the solution.
ISSN:2542-064X
2500-218X