Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II)
1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4...
Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
Published: |
Kazan Federal University
2020-03-01
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Series: | Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki |
Subjects: | |
Online Access: | https://kpfu.ru/uz-eng-ns-2020-1-3.html |
Summary: | 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4.5–5.0 and with copper(II), they form cationic mono- and binuclear complexes. Preparatively isolated copper complexes with each of the two compounds have different compositions, which also differ from the composition of complexes in the solution. |
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ISSN: | 2542-064X 2500-218X |