Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II)
1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4...
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| Format: | Article |
| Language: | English |
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Kazan Federal University
2020-03-01
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| Series: | Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki |
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| Online Access: | https://kpfu.ru/uz-eng-ns-2020-1-3.html |
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| author | V.V. Neklyudov G.A. Boos M.M. Shulaeva O.A. Lodochnikova G.A. Chmutowa E.P. Bulavina R.R. Amirov |
| author_facet | V.V. Neklyudov G.A. Boos M.M. Shulaeva O.A. Lodochnikova G.A. Chmutowa E.P. Bulavina R.R. Amirov |
| author_sort | V.V. Neklyudov |
| collection | DOAJ |
| description | 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4.5–5.0 and with copper(II), they form cationic mono- and binuclear complexes. Preparatively isolated copper complexes with each of the two compounds have different compositions, which also differ from the composition of complexes in the solution. |
| first_indexed | 2024-03-13T08:16:20Z |
| format | Article |
| id | doaj.art-25f03b2c4b6f40fcb4eb0f02cf112a99 |
| institution | Directory Open Access Journal |
| issn | 2542-064X 2500-218X |
| language | English |
| last_indexed | 2024-03-13T08:16:20Z |
| publishDate | 2020-03-01 |
| publisher | Kazan Federal University |
| record_format | Article |
| series | Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki |
| spelling | doaj.art-25f03b2c4b6f40fcb4eb0f02cf112a992023-05-31T15:09:32ZengKazan Federal UniversityUčënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki2542-064X2500-218X2020-03-011621335110.26907/2542-064X.2020.1.33-51Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II)V.V. Neklyudov0G.A. Boos1M.M. Shulaeva2O.A. Lodochnikova3G.A. Chmutowa4E.P. Bulavina5R.R. Amirov6Kazan Federal University, Kazan, 420008 RussiaKazan Federal University, Kazan, 420008 RussiaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, 420088 RussiaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, 420088 RussiaKazan Federal University, Kazan, 420008 RussiaKazan Federal University, Kazan, 420008 RussiaKazan Federal University, Kazan, 420008 Russia1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane differ by hydrocarbon spacer length, solubility in water, and polymerization tendencies. They and their amides are known to be new antitubercular agents. The substances act as polydentate ligands; in the pH range of 4.5–5.0 and with copper(II), they form cationic mono- and binuclear complexes. Preparatively isolated copper complexes with each of the two compounds have different compositions, which also differ from the composition of complexes in the solution.https://kpfu.ru/uz-eng-ns-2020-1-3.html18-bis(hydrazidomethylsulfonyl)octane10-bis(hydrazidomethylsulfonyl)decanecopper(ii)acid-base propertiescomplexationligand denticitythree-dimensional structureelemental analysisx-ray crystallography |
| spellingShingle | V.V. Neklyudov G.A. Boos M.M. Shulaeva O.A. Lodochnikova G.A. Chmutowa E.P. Bulavina R.R. Amirov Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki 1 8-bis(hydrazidomethylsulfonyl)octane 10-bis(hydrazidomethylsulfonyl)decane copper(ii) acid-base properties complexation ligand denticity three-dimensional structure elemental analysis x-ray crystallography |
| title | Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) |
| title_full | Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) |
| title_fullStr | Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) |
| title_full_unstemmed | Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) |
| title_short | Complexes of 1,8-bis(hydrazidomethylsulfonyl)octane and 1,10-bis(hydrazidomethylsulfonyl)decane with copper(II) |
| title_sort | complexes of 1 8 bis hydrazidomethylsulfo nyl octane and 1 10 bis hydrazidomethylsulfonyl decane with copper ii |
| topic | 1 8-bis(hydrazidomethylsulfonyl)octane 10-bis(hydrazidomethylsulfonyl)decane copper(ii) acid-base properties complexation ligand denticity three-dimensional structure elemental analysis x-ray crystallography |
| url | https://kpfu.ru/uz-eng-ns-2020-1-3.html |
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