Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc
The title compound, [Zn(C19H21N2)2], appears to be the first example of a zinc complex supported by two β-diketiminate (nacnac) ligands. This complex crystallizes with a distorted tetrahedrally coordinated ZnII atom that diposes the two nacnac ligands approximately orthogonally to one a...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812007878 |
| _version_ | 1798018444697796608 |
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| author | Anthony E. Wetherby Benjamin A. Vaughan Rory Waterman |
| author_facet | Anthony E. Wetherby Benjamin A. Vaughan Rory Waterman |
| author_sort | Anthony E. Wetherby |
| collection | DOAJ |
| description | The title compound, [Zn(C19H21N2)2], appears to be the first example of a zinc complex supported by two β-diketiminate (nacnac) ligands. This complex crystallizes with a distorted tetrahedrally coordinated ZnII atom that diposes the two nacnac ligands approximately orthogonally to one another [angle between the two N—Zn—N mean planes is 89.91 (10)°], with average Zn—N bond lengths of 1.992 (4) Å. |
| first_indexed | 2024-04-11T16:24:14Z |
| format | Article |
| id | doaj.art-261da9644ec04cc3992c88a2f25e41c9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:24:14Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-261da9644ec04cc3992c88a2f25e41c92022-12-22T04:14:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m343m34310.1107/S1600536812007878Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zincAnthony E. WetherbyBenjamin A. VaughanRory WatermanThe title compound, [Zn(C19H21N2)2], appears to be the first example of a zinc complex supported by two β-diketiminate (nacnac) ligands. This complex crystallizes with a distorted tetrahedrally coordinated ZnII atom that diposes the two nacnac ligands approximately orthogonally to one another [angle between the two N—Zn—N mean planes is 89.91 (10)°], with average Zn—N bond lengths of 1.992 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812007878 |
| spellingShingle | Anthony E. Wetherby Benjamin A. Vaughan Rory Waterman Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc Acta Crystallographica Section E |
| title | Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc |
| title_full | Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc |
| title_fullStr | Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc |
| title_full_unstemmed | Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc |
| title_short | Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc |
| title_sort | bis 4 methyl n 2z 4e 4 4 methylphenyl imino pent 2 en 2 yl anilinido zinc |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812007878 |
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