Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals

(Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinctio...

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Main Authors: I.P. Studenyak, S.M. Bereznyuk, M.M. Pop, V.I. Studenyak, A.I. Pogodin, O.P. Kokhan, B. Grančič, P. Kúš
Format: Article
Language:English
Published: National Academy of Sciences of Ukraine. Institute of Semi conductor physics. 2020-06-01
Series:Semiconductor Physics, Quantum Electronics & Optoelectronics
Subjects:
Online Access:http://journal-spqeo.org.ua/n2_2020/P186-192abstr.html
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author I.P. Studenyak
S.M. Bereznyuk
M.M. Pop
V.I. Studenyak
A.I. Pogodin
O.P. Kokhan
B. Grančič
P. Kúš
author_facet I.P. Studenyak
S.M. Bereznyuk
M.M. Pop
V.I. Studenyak
A.I. Pogodin
O.P. Kokhan
B. Grančič
P. Kúš
author_sort I.P. Studenyak
collection DOAJ
description (Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinction coefficients for (Cu1–хAgx)7SiS5I mixed crystals were obtained from spectral ellipsometry measurements. A nonlinear decrease of the energy pseudogap and a nonlinear behavior with the maximum of refractive index have been revealed with increasing the Ag content. The dispersion of refractive indices of (Cu1–хAgx)7SiS5I has been described in the framework of different models.
first_indexed 2024-12-13T23:40:38Z
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publisher National Academy of Sciences of Ukraine. Institute of Semi conductor physics.
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spelling doaj.art-2631aa7972ad4aa6bbe3e7209a45c5682022-12-21T23:27:10ZengNational Academy of Sciences of Ukraine. Institute of Semi conductor physics.Semiconductor Physics, Quantum Electronics & Optoelectronics1560-80341605-65822020-06-0123218619210.15407/spqeo23.02.186Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystalsI.P. Studenyak0S.M. Bereznyuk1M.M. Pop2V.I. Studenyak3A.I. Pogodin4O.P. Kokhan5B. Grančič 6P. Kúš7Uzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineComenius University, Faculty of Mathematics, Physics and Informatics, Mlynska dolina, 84248 Bratislava, Slovakia E-mail: studenyak@dr.comComenius University, Faculty of Mathematics, Physics and Informatics, Mlynska dolina, 84248 Bratislava, Slovakia E-mail: studenyak@dr.com(Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinction coefficients for (Cu1–хAgx)7SiS5I mixed crystals were obtained from spectral ellipsometry measurements. A nonlinear decrease of the energy pseudogap and a nonlinear behavior with the maximum of refractive index have been revealed with increasing the Ag content. The dispersion of refractive indices of (Cu1–хAgx)7SiS5I has been described in the framework of different models.http://journal-spqeo.org.ua/n2_2020/P186-192abstr.htmlmixed crystalspectral ellipsometryrefractive indexdiffuse reflectionenergy pseudogap
spellingShingle I.P. Studenyak
S.M. Bereznyuk
M.M. Pop
V.I. Studenyak
A.I. Pogodin
O.P. Kokhan
B. Grančič
P. Kúš
Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
Semiconductor Physics, Quantum Electronics & Optoelectronics
mixed crystal
spectral ellipsometry
refractive index
diffuse reflection
energy pseudogap
title Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
title_full Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
title_fullStr Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
title_full_unstemmed Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
title_short Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
title_sort influence of cation substitution on optical constants of cu1 xagx 7sis5i mixed crystals
topic mixed crystal
spectral ellipsometry
refractive index
diffuse reflection
energy pseudogap
url http://journal-spqeo.org.ua/n2_2020/P186-192abstr.html
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