Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals
(Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinctio...
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Format: | Article |
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National Academy of Sciences of Ukraine. Institute of Semi conductor physics.
2020-06-01
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Series: | Semiconductor Physics, Quantum Electronics & Optoelectronics |
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Online Access: | http://journal-spqeo.org.ua/n2_2020/P186-192abstr.html |
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author | I.P. Studenyak S.M. Bereznyuk M.M. Pop V.I. Studenyak A.I. Pogodin O.P. Kokhan B. Grančič P. Kúš |
author_facet | I.P. Studenyak S.M. Bereznyuk M.M. Pop V.I. Studenyak A.I. Pogodin O.P. Kokhan B. Grančič P. Kúš |
author_sort | I.P. Studenyak |
collection | DOAJ |
description | (Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinction coefficients for (Cu1–хAgx)7SiS5I mixed crystals were obtained from spectral ellipsometry measurements. A nonlinear decrease of the energy pseudogap and a nonlinear behavior with the maximum of refractive index have been revealed with increasing the Ag content. The dispersion of refractive indices of (Cu1–хAgx)7SiS5I has been described in the framework of different models. |
first_indexed | 2024-12-13T23:40:38Z |
format | Article |
id | doaj.art-2631aa7972ad4aa6bbe3e7209a45c568 |
institution | Directory Open Access Journal |
issn | 1560-8034 1605-6582 |
language | English |
last_indexed | 2024-12-13T23:40:38Z |
publishDate | 2020-06-01 |
publisher | National Academy of Sciences of Ukraine. Institute of Semi conductor physics. |
record_format | Article |
series | Semiconductor Physics, Quantum Electronics & Optoelectronics |
spelling | doaj.art-2631aa7972ad4aa6bbe3e7209a45c5682022-12-21T23:27:10ZengNational Academy of Sciences of Ukraine. Institute of Semi conductor physics.Semiconductor Physics, Quantum Electronics & Optoelectronics1560-80341605-65822020-06-0123218619210.15407/spqeo23.02.186Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystalsI.P. Studenyak0S.M. Bereznyuk1M.M. Pop2V.I. Studenyak3A.I. Pogodin4O.P. Kokhan5B. Grančič 6P. Kúš7Uzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineUzhhorod National University, Faculty of Physics, 3, Narodna Sq., 88000 Uzhhorod, UkraineComenius University, Faculty of Mathematics, Physics and Informatics, Mlynska dolina, 84248 Bratislava, Slovakia E-mail: studenyak@dr.comComenius University, Faculty of Mathematics, Physics and Informatics, Mlynska dolina, 84248 Bratislava, Slovakia E-mail: studenyak@dr.com(Cu1–хAgx)7SiS5I mixed crystals were grown using the vertical zone crystalliza-tion method, they have been shown to crystallize in cubic structure (). The diffuse reflection spectra for the powders of (Cu1–хAgx)7SiS5I mixed crystals were measured at room temperature. Refractive indices and extinction coefficients for (Cu1–хAgx)7SiS5I mixed crystals were obtained from spectral ellipsometry measurements. A nonlinear decrease of the energy pseudogap and a nonlinear behavior with the maximum of refractive index have been revealed with increasing the Ag content. The dispersion of refractive indices of (Cu1–хAgx)7SiS5I has been described in the framework of different models.http://journal-spqeo.org.ua/n2_2020/P186-192abstr.htmlmixed crystalspectral ellipsometryrefractive indexdiffuse reflectionenergy pseudogap |
spellingShingle | I.P. Studenyak S.M. Bereznyuk M.M. Pop V.I. Studenyak A.I. Pogodin O.P. Kokhan B. Grančič P. Kúš Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals Semiconductor Physics, Quantum Electronics & Optoelectronics mixed crystal spectral ellipsometry refractive index diffuse reflection energy pseudogap |
title | Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals |
title_full | Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals |
title_fullStr | Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals |
title_full_unstemmed | Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals |
title_short | Influence of cation substitution on optical constants of (Cu1-xAgx)7SiS5I mixed crystals |
title_sort | influence of cation substitution on optical constants of cu1 xagx 7sis5i mixed crystals |
topic | mixed crystal spectral ellipsometry refractive index diffuse reflection energy pseudogap |
url | http://journal-spqeo.org.ua/n2_2020/P186-192abstr.html |
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