How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?

Dye-sensitized solar cell (DSC) technology has been broadly investigated over the past few decades. The sandwich-type structure of the DSC makes the manufacturing undemanding under laboratory conditions but results in the need for reproducible measurements for acceptable DSC characterization. Electr...

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Main Authors: Mariia Becker, Maria-Sophie Bertrams, Edwin C. Constable, Catherine E. Housecroft
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/7/1547
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author Mariia Becker
Maria-Sophie Bertrams
Edwin C. Constable
Catherine E. Housecroft
author_facet Mariia Becker
Maria-Sophie Bertrams
Edwin C. Constable
Catherine E. Housecroft
author_sort Mariia Becker
collection DOAJ
description Dye-sensitized solar cell (DSC) technology has been broadly investigated over the past few decades. The sandwich-type structure of the DSC makes the manufacturing undemanding under laboratory conditions but results in the need for reproducible measurements for acceptable DSC characterization. Electrochemical impedance spectroscopy (EIS) offers the possibility to study complex electronic systems and is commonly used for solar cells. There is a tendency in the literature to present impedance data only for one representative device. At the same time, as current density–voltage plots illustrate, measurements can vary within one set of DSCs with identical components. We present multiple DSC impedance measurements on “identical” devices prepared using two different dyes and present a statistical analysis regarding the reproducibility.
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spelling doaj.art-26355d5aa9b9408a9bd8d9c942a66b002023-11-16T14:27:53ZengMDPI AGMaterials1996-19442020-03-01137154710.3390/ma13071547How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?Mariia Becker0Maria-Sophie Bertrams1Edwin C. Constable2Catherine E. Housecroft3Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandDepartment of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandDepartment of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandDepartment of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandDye-sensitized solar cell (DSC) technology has been broadly investigated over the past few decades. The sandwich-type structure of the DSC makes the manufacturing undemanding under laboratory conditions but results in the need for reproducible measurements for acceptable DSC characterization. Electrochemical impedance spectroscopy (EIS) offers the possibility to study complex electronic systems and is commonly used for solar cells. There is a tendency in the literature to present impedance data only for one representative device. At the same time, as current density–voltage plots illustrate, measurements can vary within one set of DSCs with identical components. We present multiple DSC impedance measurements on “identical” devices prepared using two different dyes and present a statistical analysis regarding the reproducibility.https://www.mdpi.com/1996-1944/13/7/1547electrochemical impedance spectroscopydye-sensitized solar cellsdyestatistical analysis
spellingShingle Mariia Becker
Maria-Sophie Bertrams
Edwin C. Constable
Catherine E. Housecroft
How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
Materials
electrochemical impedance spectroscopy
dye-sensitized solar cells
dye
statistical analysis
title How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
title_full How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
title_fullStr How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
title_full_unstemmed How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
title_short How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
title_sort how reproducible are electrochemical impedance spectroscopic data for dye sensitized solar cells
topic electrochemical impedance spectroscopy
dye-sensitized solar cells
dye
statistical analysis
url https://www.mdpi.com/1996-1944/13/7/1547
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