Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review

With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle...

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Main Authors: Zhan eLin, Gaoran eLi, Zhoupeng eLi, Bin eZhang
Format: Article
Language:English
Published: Frontiers Media S.A. 2015-02-01
Series:Frontiers in Energy Research
Subjects:
Online Access:http://journal.frontiersin.org/Journal/10.3389/fenrg.2015.00005/full
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author Zhan eLin
Gaoran eLi
Zhoupeng eLi
Bin eZhang
author_facet Zhan eLin
Gaoran eLi
Zhoupeng eLi
Bin eZhang
author_sort Zhan eLin
collection DOAJ
description With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.
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spelling doaj.art-2648a9aae7ad4a6ca781f4ba9662ff652022-12-21T19:01:11ZengFrontiers Media S.A.Frontiers in Energy Research2296-598X2015-02-01310.3389/fenrg.2015.00005126527Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A ReviewZhan eLin0Gaoran eLi1Zhoupeng eLi2Bin eZhang3Zhejiang UniversityZhejiang UniversityZhejiang UniversityAnhui Academy for Environmental Science ResearchWith a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.http://journal.frontiersin.org/Journal/10.3389/fenrg.2015.00005/fullElectrolytesreviewenergy storagepolysulfideLi-S batteries
spellingShingle Zhan eLin
Gaoran eLi
Zhoupeng eLi
Bin eZhang
Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
Frontiers in Energy Research
Electrolytes
review
energy storage
polysulfide
Li-S batteries
title Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
title_full Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
title_fullStr Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
title_full_unstemmed Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
title_short Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
title_sort developments of electrolyte systems for lithium sulfur batteries a review
topic Electrolytes
review
energy storage
polysulfide
Li-S batteries
url http://journal.frontiersin.org/Journal/10.3389/fenrg.2015.00005/full
work_keys_str_mv AT zhanelin developmentsofelectrolytesystemsforlithiumsulfurbatteriesareview
AT gaoraneli developmentsofelectrolytesystemsforlithiumsulfurbatteriesareview
AT zhoupengeli developmentsofelectrolytesystemsforlithiumsulfurbatteriesareview
AT binezhang developmentsofelectrolytesystemsforlithiumsulfurbatteriesareview