Tetragonal-to-Tetragonal Phase Transition in Lead-Free (KxNa1−x)NbO3 (x = 0.11 and 0.17) Crystals

Lead free piezoelectric crystals of (KxNa1−x)NbO3 (x = 0.11 and 0.17) have been grown by the modified Bridgman method. The structure and chemical composition of the obtained crystals were determined by X-ray diffraction (XRD) and electron probe microanalysis (EPMA). The domain structure evolution wi...

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Bibliographic Details
Main Authors: Dabin Lin, Zhenrong Li, Fei Li, Changlong Cai, Weiguo Liu, Shujun Zhang
Format: Article
Language:English
Published: MDPI AG 2014-06-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/4/2/113
Description
Summary:Lead free piezoelectric crystals of (KxNa1−x)NbO3 (x = 0.11 and 0.17) have been grown by the modified Bridgman method. The structure and chemical composition of the obtained crystals were determined by X-ray diffraction (XRD) and electron probe microanalysis (EPMA). The domain structure evolution with increasing temperature for (KxNa1−x)NbO3 (x = 0.11 and 0.17) crystals was observed using polarized light microscopy (PLM), where distinguished changes of the domain structures were found to occur at 400 °C and 412 °C respectively, corresponding to the tetragonal to tetragonal phase transition temperatures. Dielectric measurements performed on (K0.11Na0.89)NbO3 crystals exhibited tetragonal to tetragonal and tetragonal to cubic phase transitions temperatures at 405 °C and 496 °C, respectively.
ISSN:2073-4352