Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean

A procedure for experimental modeling of sorption–desorption processes in the mixing zone of river and sea waters, which excludes the determination of the absolute concentrations of adsorbed chemical elements, has been proposed. Based on experimental data, quantitative characteristics of the ion-exc...

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Main Authors: Alla V. Savenko, Vitaly S. Savenko
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/4/445
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author Alla V. Savenko
Vitaly S. Savenko
author_facet Alla V. Savenko
Vitaly S. Savenko
author_sort Alla V. Savenko
collection DOAJ
description A procedure for experimental modeling of sorption–desorption processes in the mixing zone of river and sea waters, which excludes the determination of the absolute concentrations of adsorbed chemical elements, has been proposed. Based on experimental data, quantitative characteristics of the ion-exchange transformation of dissolved matter runoff during the penetration of terrigenous material into the marine environment were obtained. The real input of calcium into the ocean as a result of desorption from the solid substances of river runoff increases by 8.3–8.7%, while input of sodium, potassium, and magnesium decreases by 14.0–14.6, 22.2–23.3, and 3.0–3.2% of their dissolved river runoff. For trace elements, sorption–desorption processes lead to an increase in the runoff of dissolved manganese, cobalt, nickel, cadmium, thallium, barium, and ammonium by 98.6–103.5, 20.6–21.6, 3.8–4.0, 15.6–16.5, 4.7–4.9, 20.3–21.3, and 0.8% and to a decrease in the runoff of dissolved lead and cesium by 9.1–9.4 and 2.6–2.8%.
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spelling doaj.art-2695b96a909c46729263211960ff0cb52023-12-03T13:45:39ZengMDPI AGMinerals2075-163X2022-04-0112444510.3390/min12040445Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the OceanAlla V. Savenko0Vitaly S. Savenko1Faculty of Geology, Lomonosov Moscow State University, 119991 Moscow, RussiaFaculty of Geography, Lomonosov Moscow State University, 119991 Moscow, RussiaA procedure for experimental modeling of sorption–desorption processes in the mixing zone of river and sea waters, which excludes the determination of the absolute concentrations of adsorbed chemical elements, has been proposed. Based on experimental data, quantitative characteristics of the ion-exchange transformation of dissolved matter runoff during the penetration of terrigenous material into the marine environment were obtained. The real input of calcium into the ocean as a result of desorption from the solid substances of river runoff increases by 8.3–8.7%, while input of sodium, potassium, and magnesium decreases by 14.0–14.6, 22.2–23.3, and 3.0–3.2% of their dissolved river runoff. For trace elements, sorption–desorption processes lead to an increase in the runoff of dissolved manganese, cobalt, nickel, cadmium, thallium, barium, and ammonium by 98.6–103.5, 20.6–21.6, 3.8–4.0, 15.6–16.5, 4.7–4.9, 20.3–21.3, and 0.8% and to a decrease in the runoff of dissolved lead and cesium by 9.1–9.4 and 2.6–2.8%.https://www.mdpi.com/2075-163X/12/4/445sorption–desorption processesmixing zone of river and sea watersmajor cationstrace elements
spellingShingle Alla V. Savenko
Vitaly S. Savenko
Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
Minerals
sorption–desorption processes
mixing zone of river and sea waters
major cations
trace elements
title Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
title_full Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
title_fullStr Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
title_full_unstemmed Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
title_short Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean
title_sort adsorbed chemical elements of river runoff of solids and their role in the transformation of dissolved matter runoff into the ocean
topic sorption–desorption processes
mixing zone of river and sea waters
major cations
trace elements
url https://www.mdpi.com/2075-163X/12/4/445
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