Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel

With the rapid growth in fuel demand, deep desulfurization of fuel oil is vitally necessary for the sake of health and environmental protection. In this work, a kind of magnetic ionic liquid supported silica is prepared by a facile ball milling method, and applied in the aerobic oxidative desulfuriz...

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Main Authors: Fujie Liu, Ming Zhang, Yongkang Gao, Haojie Tan, Hongping Li, Chao Wang, Wenshuai Zhu, Huaming Li
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/11/12/1496
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author Fujie Liu
Ming Zhang
Yongkang Gao
Haojie Tan
Hongping Li
Chao Wang
Wenshuai Zhu
Huaming Li
author_facet Fujie Liu
Ming Zhang
Yongkang Gao
Haojie Tan
Hongping Li
Chao Wang
Wenshuai Zhu
Huaming Li
author_sort Fujie Liu
collection DOAJ
description With the rapid growth in fuel demand, deep desulfurization of fuel oil is vitally necessary for the sake of health and environmental protection. In this work, a kind of magnetic ionic liquid supported silica is prepared by a facile ball milling method, and applied in the aerobic oxidative desulfurization of organosulfurs in fuel. The experimental results indicated that ball milling procedure can increase the specific surface area of samples, which is beneficial to oxidative desulfurization process. Under the optimal reaction conditions, the prepared materials can have an entire removal of aromatic sulfur compounds as well as a good recycling ability. Moreover, the introduction of Fe<sub>3</sub>O<sub>4</sub> did not decline the desulfurization performance, but help the catalyst to be easily separated after reaction.
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spelling doaj.art-26b20dd3284c4a5eb5a122262b19141d2023-11-23T07:34:29ZengMDPI AGCatalysts2073-43442021-12-011112149610.3390/catal11121496Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in FuelFujie Liu0Ming Zhang1Yongkang Gao2Haojie Tan3Hongping Li4Chao Wang5Wenshuai Zhu6Huaming Li7Zhenjiang Key Laboratory of Functional Chemistry, Institute of Medicine and Chemical Engineering, Zhenjiang College, Zhenjiang 212028, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaJingjiang College, Jiangsu University, Zhenjiang 212114, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaInstitute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, ChinaWith the rapid growth in fuel demand, deep desulfurization of fuel oil is vitally necessary for the sake of health and environmental protection. In this work, a kind of magnetic ionic liquid supported silica is prepared by a facile ball milling method, and applied in the aerobic oxidative desulfurization of organosulfurs in fuel. The experimental results indicated that ball milling procedure can increase the specific surface area of samples, which is beneficial to oxidative desulfurization process. Under the optimal reaction conditions, the prepared materials can have an entire removal of aromatic sulfur compounds as well as a good recycling ability. Moreover, the introduction of Fe<sub>3</sub>O<sub>4</sub> did not decline the desulfurization performance, but help the catalyst to be easily separated after reaction.https://www.mdpi.com/2073-4344/11/12/1496polyoxometalateionic liquidsilicamagnetic materialsball milling
spellingShingle Fujie Liu
Ming Zhang
Yongkang Gao
Haojie Tan
Hongping Li
Chao Wang
Wenshuai Zhu
Huaming Li
Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
Catalysts
polyoxometalate
ionic liquid
silica
magnetic materials
ball milling
title Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
title_full Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
title_fullStr Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
title_full_unstemmed Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
title_short Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel
title_sort facile construction of magnetic ionic liquid supported silica for aerobic oxidative desulfurization in fuel
topic polyoxometalate
ionic liquid
silica
magnetic materials
ball milling
url https://www.mdpi.com/2073-4344/11/12/1496
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