Influence of Cu-doped TiO2 on its structural and photocatalytic properties
Due to the potential of heterogeneous photocatalysis for wastewater treatment, the researches concerning the improvement materials modifications for its photocatalytic activity have been widely increased. One of the most employed methods is the metal doping into semiconductors. Herewith, we demonstr...
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Format: | Article |
Language: | English |
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Universidade Estadual Paulista
2022-04-01
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Series: | Eclética Química |
Online Access: | https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1269 |
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author | Vinícius Teodoro Elson Longo Maria Aparecida Zaghete Leinig Antonio Perazolli |
author_facet | Vinícius Teodoro Elson Longo Maria Aparecida Zaghete Leinig Antonio Perazolli |
author_sort | Vinícius Teodoro |
collection | DOAJ |
description | Due to the potential of heterogeneous photocatalysis for wastewater treatment, the researches concerning the improvement materials modifications for its photocatalytic activity have been widely increased. One of the most employed methods is the metal doping into semiconductors. Herewith, we demonstrated the influence of Cu doping into TiO2 in its photocatalytic properties. The powder samples with 0.0 to 0.7% mol were obtained by the Pechini method and characterized by XRD, micro-Raman spectroscopy, FE-SEM, and photoluminescence spectroscopy. The Cu insertion into TiO2 structure induced the stabilization of anatase phase, increasing its content in the samples in relation to the bare TiO2. The PL results indicated that a decrease in the PL emission intensity and a shift of the emission band to the blue region. The photocatalytic activity for rhodamine B degradation under UV light irradiation indicated that the Cu-doping into TiO2 led to an enhancement of the photocatalytic activity compared to the bare one. |
first_indexed | 2024-04-13T13:43:07Z |
format | Article |
id | doaj.art-26c7d1c1c2294568afa08607440ddc4b |
institution | Directory Open Access Journal |
issn | 0100-4670 1678-4618 |
language | English |
last_indexed | 2024-04-13T13:43:07Z |
publishDate | 2022-04-01 |
publisher | Universidade Estadual Paulista |
record_format | Article |
series | Eclética Química |
spelling | doaj.art-26c7d1c1c2294568afa08607440ddc4b2022-12-22T02:44:35ZengUniversidade Estadual PaulistaEclética Química0100-46701678-46182022-04-01471SI13014010.26850/1678-4618eqj.v47.1SI.2022.p130-140276Influence of Cu-doped TiO2 on its structural and photocatalytic propertiesVinícius Teodoro0https://orcid.org/0000-0002-6612-1978Elson Longo1https://orcid.org/0000-0001-8062-7791Maria Aparecida Zaghete2https://orcid.org/0000-0002-5867-1443Leinig Antonio Perazolli3https://orcid.org/0000-0003-1153-2742Federal University of Sao Carlos, Center for the Development of Functional Materials, São Carlos, Brazil.Federal University of Sao Carlos, Center for the Development of Functional Materials, São Carlos, Brazil.São Paulo State University, Institute of Chemistry, Araraquara, Brazil.São Paulo State University, Institute of Chemistry, Araraquara, Brazil.Due to the potential of heterogeneous photocatalysis for wastewater treatment, the researches concerning the improvement materials modifications for its photocatalytic activity have been widely increased. One of the most employed methods is the metal doping into semiconductors. Herewith, we demonstrated the influence of Cu doping into TiO2 in its photocatalytic properties. The powder samples with 0.0 to 0.7% mol were obtained by the Pechini method and characterized by XRD, micro-Raman spectroscopy, FE-SEM, and photoluminescence spectroscopy. The Cu insertion into TiO2 structure induced the stabilization of anatase phase, increasing its content in the samples in relation to the bare TiO2. The PL results indicated that a decrease in the PL emission intensity and a shift of the emission band to the blue region. The photocatalytic activity for rhodamine B degradation under UV light irradiation indicated that the Cu-doping into TiO2 led to an enhancement of the photocatalytic activity compared to the bare one.https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1269 |
spellingShingle | Vinícius Teodoro Elson Longo Maria Aparecida Zaghete Leinig Antonio Perazolli Influence of Cu-doped TiO2 on its structural and photocatalytic properties Eclética Química |
title | Influence of Cu-doped TiO2 on its structural and photocatalytic properties |
title_full | Influence of Cu-doped TiO2 on its structural and photocatalytic properties |
title_fullStr | Influence of Cu-doped TiO2 on its structural and photocatalytic properties |
title_full_unstemmed | Influence of Cu-doped TiO2 on its structural and photocatalytic properties |
title_short | Influence of Cu-doped TiO2 on its structural and photocatalytic properties |
title_sort | influence of cu doped tio2 on its structural and photocatalytic properties |
url | https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1269 |
work_keys_str_mv | AT viniciusteodoro influenceofcudopedtio2onitsstructuralandphotocatalyticproperties AT elsonlongo influenceofcudopedtio2onitsstructuralandphotocatalyticproperties AT mariaaparecidazaghete influenceofcudopedtio2onitsstructuralandphotocatalyticproperties AT leinigantonioperazolli influenceofcudopedtio2onitsstructuralandphotocatalyticproperties |