A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine

Role of Pharmacologically important compounds (Nicotinamide and Penicillamine) as ligand has been focused on the coordination complexes with with transition metal ions such as Fe(II), Co(II), Ni(II), Cu(II) and Zn(II). Complexation of metal ions with Nicotinamide as primary ligand whereas Penicillam...

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Main Author: Dr. Shivaji Laxman Jadhav
Format: Article
Language:English
Published: PURKH 2019-04-01
Series:To Chemistry Journal
Subjects:
Online Access:https://purkh.com/index.php/tochem/article/view/341
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author Dr. Shivaji Laxman Jadhav
author_facet Dr. Shivaji Laxman Jadhav
author_sort Dr. Shivaji Laxman Jadhav
collection DOAJ
description Role of Pharmacologically important compounds (Nicotinamide and Penicillamine) as ligand has been focused on the coordination complexes with with transition metal ions such as Fe(II), Co(II), Ni(II), Cu(II) and Zn(II). Complexation of metal ions with Nicotinamide as primary ligand whereas Penicillamine as secondary ligand has been evaluated by the potentiometric technique at 25±0.1°C and 0.1M (NaClO4) ionic strength. The protonation constants of the ligand were calculated from the half integral method of potentiometric pH titrations data of solutions according to Irving and Rossetti’s method.
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spelling doaj.art-26e0e5e6187747fcac99e6d1636b28f52022-12-22T00:09:14ZengPURKHTo Chemistry Journal2581-75072019-04-012341A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and PenicillamineDr. Shivaji Laxman Jadhav0Tarai College of Arts and Science, Paithan, Aurangabad (MH)Role of Pharmacologically important compounds (Nicotinamide and Penicillamine) as ligand has been focused on the coordination complexes with with transition metal ions such as Fe(II), Co(II), Ni(II), Cu(II) and Zn(II). Complexation of metal ions with Nicotinamide as primary ligand whereas Penicillamine as secondary ligand has been evaluated by the potentiometric technique at 25±0.1°C and 0.1M (NaClO4) ionic strength. The protonation constants of the ligand were calculated from the half integral method of potentiometric pH titrations data of solutions according to Irving and Rossetti’s method.https://purkh.com/index.php/tochem/article/view/341Stability constantNicotinamidePenicillaminemixed ligand complexes
spellingShingle Dr. Shivaji Laxman Jadhav
A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
To Chemistry Journal
Stability constant
Nicotinamide
Penicillamine
mixed ligand complexes
title A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
title_full A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
title_fullStr A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
title_full_unstemmed A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
title_short A pH-Metric Study of Stability Constant of ternary Complexes Involving Transition Metals, Nicotinamide and Penicillamine
title_sort ph metric study of stability constant of ternary complexes involving transition metals nicotinamide and penicillamine
topic Stability constant
Nicotinamide
Penicillamine
mixed ligand complexes
url https://purkh.com/index.php/tochem/article/view/341
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AT drshivajilaxmanjadhav phmetricstudyofstabilityconstantofternarycomplexesinvolvingtransitionmetalsnicotinamideandpenicillamine