Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>]
We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>]. By applying an external pressure (up to 3 kbar), we were able to tune the charge transport p...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-07-01
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| Series: | Magnetochemistry |
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| Online Access: | https://www.mdpi.com/2312-7481/6/3/31 |
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| author | Andrei-Cristian Gheorghe Yurii S. Bibik Olesia I. Kucheriv Diana D. Barakhtii Marin-Vlad Boicu Ionela Rusu Andrei Diaconu Il’ya A. Gural’skiy Gábor Molnár Aurelian Rotaru |
| author_facet | Andrei-Cristian Gheorghe Yurii S. Bibik Olesia I. Kucheriv Diana D. Barakhtii Marin-Vlad Boicu Ionela Rusu Andrei Diaconu Il’ya A. Gural’skiy Gábor Molnár Aurelian Rotaru |
| author_sort | Andrei-Cristian Gheorghe |
| collection | DOAJ |
| description | We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>]. By applying an external pressure (up to 3 kbar), we were able to tune the charge transport properties of the material from a more conductive low spin state to a crossover point toward a more conductive high spin state. We rationalize these results by taking into account the spin-state dependence of the activation parameters of the conductivity. |
| first_indexed | 2024-03-10T18:02:53Z |
| format | Article |
| id | doaj.art-26f1954330c147669d5e8bd3de6011c6 |
| institution | Directory Open Access Journal |
| issn | 2312-7481 |
| language | English |
| last_indexed | 2024-03-10T18:02:53Z |
| publishDate | 2020-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Magnetochemistry |
| spelling | doaj.art-26f1954330c147669d5e8bd3de6011c62023-11-20T08:42:38ZengMDPI AGMagnetochemistry2312-74812020-07-01633110.3390/magnetochemistry6030031Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>]Andrei-Cristian Gheorghe0Yurii S. Bibik1Olesia I. Kucheriv2Diana D. Barakhtii3Marin-Vlad Boicu4Ionela Rusu5Andrei Diaconu6Il’ya A. Gural’skiy7Gábor Molnár8Aurelian Rotaru9Faculty of Electrical Engineering and Computer Science & MANSiD Research Center, Stefan cel Mare University, 13, Str. Universitatii, 720229 Suceava, RomaniaDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., 01601 Kyiv, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., 01601 Kyiv, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., 01601 Kyiv, UkraineFaculty of Electrical Engineering and Computer Science & MANSiD Research Center, Stefan cel Mare University, 13, Str. Universitatii, 720229 Suceava, RomaniaFaculty of Electrical Engineering and Computer Science & MANSiD Research Center, Stefan cel Mare University, 13, Str. Universitatii, 720229 Suceava, RomaniaFaculty of Electrical Engineering and Computer Science & MANSiD Research Center, Stefan cel Mare University, 13, Str. Universitatii, 720229 Suceava, RomaniaDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., 01601 Kyiv, UkraineLCC, CNRS and Université de Toulouse, UPS, INP, F-31077 Toulouse, FranceFaculty of Electrical Engineering and Computer Science & MANSiD Research Center, Stefan cel Mare University, 13, Str. Universitatii, 720229 Suceava, RomaniaWe studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>]. By applying an external pressure (up to 3 kbar), we were able to tune the charge transport properties of the material from a more conductive low spin state to a crossover point toward a more conductive high spin state. We rationalize these results by taking into account the spin-state dependence of the activation parameters of the conductivity.https://www.mdpi.com/2312-7481/6/3/31spin crossovercharge transporthigh pressure |
| spellingShingle | Andrei-Cristian Gheorghe Yurii S. Bibik Olesia I. Kucheriv Diana D. Barakhtii Marin-Vlad Boicu Ionela Rusu Andrei Diaconu Il’ya A. Gural’skiy Gábor Molnár Aurelian Rotaru Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] Magnetochemistry spin crossover charge transport high pressure |
| title | Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] |
| title_full | Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] |
| title_fullStr | Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] |
| title_full_unstemmed | Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] |
| title_short | Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)<sub>2</sub>}<sub>2</sub>] |
| title_sort | anomalous pressure effects on the electrical conductivity of the spin crossover complex fe pyrazine au cn sub 2 sub sub 2 sub |
| topic | spin crossover charge transport high pressure |
| url | https://www.mdpi.com/2312-7481/6/3/31 |
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