The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media
The kinetics of the oxidation of benzaldehyde and para-substituted benzaldehydes by quinolinium chlorochromate in water-dimethylformamide mixtures has been studied under pseudo-first-order conditions at 25±0.2ºC. The operation of non-specific and specific solvent-solute interactions was explored by...
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| Format: | Article |
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Serbian Chemical Society
2002-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2002/0352-51390212803J.pdf |
| _version_ | 1818865880400920576 |
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| author | Jeyanthi Fatima G. Vijayakiiinarand G. Elango K.P. |
| author_facet | Jeyanthi Fatima G. Vijayakiiinarand G. Elango K.P. |
| author_sort | Jeyanthi Fatima G. |
| collection | DOAJ |
| description | The kinetics of the oxidation of benzaldehyde and para-substituted benzaldehydes by quinolinium chlorochromate in water-dimethylformamide mixtures has been studied under pseudo-first-order conditions at 25±0.2ºC. The operation of non-specific and specific solvent-solute interactions was explored by correlating the rate data with solvent parameters through a correlation analysis technique. Both electron-releasing and electron-withdrawing substitutents enhance the rate of oxidation and the Hammett plot shows a break in the reactivity order indicating the applicability of a dual mechanism. |
| first_indexed | 2024-12-19T10:54:35Z |
| format | Article |
| id | doaj.art-26f77fc505e34cb69881e0f83a4e0857 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T10:54:35Z |
| publishDate | 2002-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-26f77fc505e34cb69881e0f83a4e08572022-12-21T20:24:52ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212002-01-01671280380810.2298/JSC0212803J0352-51390212803JThe effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent mediaJeyanthi Fatima G.0Vijayakiiinarand G.1Elango K.P.2Gandhigram Rural Institute (Deemed University) - Department of Chemistry, Gandhigram, IndiaGandhigram Rural Institute (Deemed University) - Department of Chemistry, Gandhigram, IndiaAF Gandhigram Rural Institute (Deemed University) - Department of Chemistry, Gandhigram, IndiaThe kinetics of the oxidation of benzaldehyde and para-substituted benzaldehydes by quinolinium chlorochromate in water-dimethylformamide mixtures has been studied under pseudo-first-order conditions at 25±0.2ºC. The operation of non-specific and specific solvent-solute interactions was explored by correlating the rate data with solvent parameters through a correlation analysis technique. Both electron-releasing and electron-withdrawing substitutents enhance the rate of oxidation and the Hammett plot shows a break in the reactivity order indicating the applicability of a dual mechanism.http://www.doiserbia.nb.rs/img/doi/0352-5139/2002/0352-51390212803J.pdfkineticssolvent effectstructural effectbenzaldehydeoxidation. |
| spellingShingle | Jeyanthi Fatima G. Vijayakiiinarand G. Elango K.P. The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media Journal of the Serbian Chemical Society kinetics solvent effect structural effect benzaldehyde oxidation. |
| title | The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| title_full | The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| title_fullStr | The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| title_full_unstemmed | The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| title_short | The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| title_sort | effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media |
| topic | kinetics solvent effect structural effect benzaldehyde oxidation. |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2002/0352-51390212803J.pdf |
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