Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid

This work reports the attempts to carry out pulsed laser ablation in liquid (PLAL) for synthesizing colloidal copper oxide nanoparticles (NPs). Copper oxide NPs was synthesized by 7ns Nd:YAG laser ablation of high purity copper target immersed in different solutions; ethanol, acetone, and water. The...

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Main Authors: Abdul Qader D. Faisal, Raid A. Ismail, Zainab N. Jameel
Format: Article
Language:English
Published: Unviversity of Technology- Iraq 2013-01-01
Series:Engineering and Technology Journal
Subjects:
Online Access:https://etj.uotechnology.edu.iq/article_83947_30bf6449b0fc6c9e2bacb81464346dcc.pdf
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author Abdul Qader D. Faisal
Raid A. Ismail
Zainab N. Jameel
author_facet Abdul Qader D. Faisal
Raid A. Ismail
Zainab N. Jameel
author_sort Abdul Qader D. Faisal
collection DOAJ
description This work reports the attempts to carry out pulsed laser ablation in liquid (PLAL) for synthesizing colloidal copper oxide nanoparticles (NPs). Copper oxide NPs was synthesized by 7ns Nd:YAG laser ablation of high purity copper target immersed in different solutions; ethanol, acetone, and water. The optical and morphological properties of copper oxide NPs were investigated. It was found that the optical absorbance, energy gap, size, and distribution of copper oxide nanoparticles are dependent on liquid type. Plasmon peak was observed at 550nm for Cu NPs ablated in acetone and methanol liquids, while it was disappeared for those ablated in water. Atomic Force Microscopy (AFM) analysis showed that the average grain size of copper oxide particles ablated in acetone, ethanol, and water were 276 nm, 300, and 360nm, respectively. Fourier Transform Infrared (FTIR) was used to study the vibrational frequencies between the bonds of atoms for a synthesized copper oxide NPs at different liquids. All these results confirm the complete oxidation of ablated copper.
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spelling doaj.art-26f8aafbe1c848b9b75b4d3b214de1cb2024-02-04T17:34:06ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582013-01-01311B142310.30684/etj.31.1B.383947Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in LiquidAbdul Qader D. FaisalRaid A. IsmailZainab N. JameelThis work reports the attempts to carry out pulsed laser ablation in liquid (PLAL) for synthesizing colloidal copper oxide nanoparticles (NPs). Copper oxide NPs was synthesized by 7ns Nd:YAG laser ablation of high purity copper target immersed in different solutions; ethanol, acetone, and water. The optical and morphological properties of copper oxide NPs were investigated. It was found that the optical absorbance, energy gap, size, and distribution of copper oxide nanoparticles are dependent on liquid type. Plasmon peak was observed at 550nm for Cu NPs ablated in acetone and methanol liquids, while it was disappeared for those ablated in water. Atomic Force Microscopy (AFM) analysis showed that the average grain size of copper oxide particles ablated in acetone, ethanol, and water were 276 nm, 300, and 360nm, respectively. Fourier Transform Infrared (FTIR) was used to study the vibrational frequencies between the bonds of atoms for a synthesized copper oxide NPs at different liquids. All these results confirm the complete oxidation of ablated copper.https://etj.uotechnology.edu.iq/article_83947_30bf6449b0fc6c9e2bacb81464346dcc.pdflaser ablationcopper oxidenanoparticlesliquidsafmftir
spellingShingle Abdul Qader D. Faisal
Raid A. Ismail
Zainab N. Jameel
Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
Engineering and Technology Journal
laser ablation
copper oxide
nanoparticles
liquids
afm
ftir
title Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
title_full Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
title_fullStr Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
title_full_unstemmed Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
title_short Synthesis of Colloidal Copper Oxide Nan Oparticles Using Pulsed Nd:YAG Laser Ablation in Liquid
title_sort synthesis of colloidal copper oxide nan oparticles using pulsed nd yag laser ablation in liquid
topic laser ablation
copper oxide
nanoparticles
liquids
afm
ftir
url https://etj.uotechnology.edu.iq/article_83947_30bf6449b0fc6c9e2bacb81464346dcc.pdf
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AT raidaismail synthesisofcolloidalcopperoxidenanoparticlesusingpulsedndyaglaserablationinliquid
AT zainabnjameel synthesisofcolloidalcopperoxidenanoparticlesusingpulsedndyaglaserablationinliquid