Improving the properties of naphtha using a mixed catalyst prepared from natural ore

AbstractCatalysts are involved in many industries and due to their high cost, therefore, the research was directed to the exploitation of environmentally friendly materials, which are the natural raw materials that are available in large quantities in the Western Desert region of Anbar, in the prepa...

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Main Authors: Abbas Rafaa, Qaidar Salim
Format: Article
Language:Arabic
Published: College of Education for Pure Sciences 2023-06-01
Series:مجلة التربية والعلم
Subjects:
Online Access:https://edusj.mosuljournals.com/article_178420_7154359807873e9682d99fd23978c2de.pdf
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author Abbas Rafaa
Qaidar Salim
author_facet Abbas Rafaa
Qaidar Salim
author_sort Abbas Rafaa
collection DOAJ
description AbstractCatalysts are involved in many industries and due to their high cost, therefore, the research was directed to the exploitation of environmentally friendly materials, which are the natural raw materials that are available in large quantities in the Western Desert region of Anbar, in the preparation of the catalyst support material under study (alumina). Where the ore was exploited after conducting a series of treatments to prepare alumina as a dominant material for the catalyst prepared from platinum and palladium. The catalyst was used in the gaseous treatment of naphtha (58 - 160 °C) at different conditions of temperature, reaction time and the percentage of catalyst added, and after determining the optimal conditions for the catalytic treatment by analyzing the results of infrared (IR) measurement according to the initial conditions, it was found that the best treatment conditions were at a temperature of (250 °C), a reaction time of (2 hours), and a catalyst ratio of (2%), where the catalyst showed high effectiveness towards the reactions of structural reformation and hydrogen removal, in addition to that, a nuclear magnetic resonance spectroscopy (NMR) was measured ( 1HNMR) and gas chromatography (GC) for both untreated and treated naphtha under optimal conditions for the purpose of identifying the nature of structural changes of different hydrocarbon compounds (PONA) and estimating the ratio of methylene, methylene and aromatic protons, respectively. The results showed the effectiveness of the catalyst towards the reactions of structural reforming and dehydrogenation through the formation of aromatic and olefinic compounds.
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spelling doaj.art-27353c6482a94ec28109d3b84e4426212023-05-30T23:24:20ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302023-06-0132213414610.33899/edusj.2023.139016.1344178420Improving the properties of naphtha using a mixed catalyst prepared from natural oreAbbas Rafaa0Qaidar Salim1Department of Chemistry, College of Education for Pure Science, University of Mosul, Mosul, IraqDepartment of Chemistry, College of Education for Pure Science, University of Mosul, Mosul, IraqAbstractCatalysts are involved in many industries and due to their high cost, therefore, the research was directed to the exploitation of environmentally friendly materials, which are the natural raw materials that are available in large quantities in the Western Desert region of Anbar, in the preparation of the catalyst support material under study (alumina). Where the ore was exploited after conducting a series of treatments to prepare alumina as a dominant material for the catalyst prepared from platinum and palladium. The catalyst was used in the gaseous treatment of naphtha (58 - 160 °C) at different conditions of temperature, reaction time and the percentage of catalyst added, and after determining the optimal conditions for the catalytic treatment by analyzing the results of infrared (IR) measurement according to the initial conditions, it was found that the best treatment conditions were at a temperature of (250 °C), a reaction time of (2 hours), and a catalyst ratio of (2%), where the catalyst showed high effectiveness towards the reactions of structural reformation and hydrogen removal, in addition to that, a nuclear magnetic resonance spectroscopy (NMR) was measured ( 1HNMR) and gas chromatography (GC) for both untreated and treated naphtha under optimal conditions for the purpose of identifying the nature of structural changes of different hydrocarbon compounds (PONA) and estimating the ratio of methylene, methylene and aromatic protons, respectively. The results showed the effectiveness of the catalyst towards the reactions of structural reforming and dehydrogenation through the formation of aromatic and olefinic compounds.https://edusj.mosuljournals.com/article_178420_7154359807873e9682d99fd23978c2de.pdfbauxite,,,،؛naphtha,,,،؛catalyst,,,،؛alumina
spellingShingle Abbas Rafaa
Qaidar Salim
Improving the properties of naphtha using a mixed catalyst prepared from natural ore
مجلة التربية والعلم
bauxite,,
,،؛naphtha,,
,،؛catalyst,,
,،؛alumina
title Improving the properties of naphtha using a mixed catalyst prepared from natural ore
title_full Improving the properties of naphtha using a mixed catalyst prepared from natural ore
title_fullStr Improving the properties of naphtha using a mixed catalyst prepared from natural ore
title_full_unstemmed Improving the properties of naphtha using a mixed catalyst prepared from natural ore
title_short Improving the properties of naphtha using a mixed catalyst prepared from natural ore
title_sort improving the properties of naphtha using a mixed catalyst prepared from natural ore
topic bauxite,,
,،؛naphtha,,
,،؛catalyst,,
,،؛alumina
url https://edusj.mosuljournals.com/article_178420_7154359807873e9682d99fd23978c2de.pdf
work_keys_str_mv AT abbasrafaa improvingthepropertiesofnaphthausingamixedcatalystpreparedfromnaturalore
AT qaidarsalim improvingthepropertiesofnaphthausingamixedcatalystpreparedfromnaturalore