Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach
The reaction between diaminomaleonitrile (DAMN) and aldehydes and the resulting monoimines are well known. Since the standard reaction conditions involve the use of toxic solvents (typically methanol), we have sought to apply green chemistry principles to this reaction by either using water as the s...
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| Format: | Article |
| Language: | English |
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MDPI AG
2006-11-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/11/11/858/ |
| _version_ | 1819315828421558272 |
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| author | Francisco León Jaime RÃÂos-Motta RÃÂos-Motta Augusto Rivera |
| author_facet | Francisco León Jaime RÃÂos-Motta RÃÂos-Motta Augusto Rivera |
| author_sort | Francisco León |
| collection | DOAJ |
| description | The reaction between diaminomaleonitrile (DAMN) and aldehydes and the resulting monoimines are well known. Since the standard reaction conditions involve the use of toxic solvents (typically methanol), we have sought to apply green chemistry principles to this reaction by either using water as the solvent without any catalysts or employing “solvent-free†conditions. The monoimines derived from DAMN are of interest as precursors for obtaining different heterocyclic systems and linear polymers. The methodologies used have significant advantages with regards to cost and environmental considerations. |
| first_indexed | 2024-12-24T10:06:18Z |
| format | Article |
| id | doaj.art-274e0fc8929340fcbddabaacf820178f |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-24T10:06:18Z |
| publishDate | 2006-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-274e0fc8929340fcbddabaacf820178f2022-12-21T17:00:46ZengMDPI AGMolecules1420-30492006-11-01111185886610.3390/11110858Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry ApproachFrancisco LeónJaime RÃÂos-Motta RÃÂos-MottaAugusto RiveraThe reaction between diaminomaleonitrile (DAMN) and aldehydes and the resulting monoimines are well known. Since the standard reaction conditions involve the use of toxic solvents (typically methanol), we have sought to apply green chemistry principles to this reaction by either using water as the solvent without any catalysts or employing “solvent-free†conditions. The monoimines derived from DAMN are of interest as precursors for obtaining different heterocyclic systems and linear polymers. The methodologies used have significant advantages with regards to cost and environmental considerations.http://www.mdpi.com/1420-3049/11/11/858/DAMNmonoiminesGreen Chemistryaromatic aldehydes. |
| spellingShingle | Francisco León Jaime RÃÂos-Motta RÃÂos-Motta Augusto Rivera Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach Molecules DAMN monoimines Green Chemistry aromatic aldehydes. |
| title | Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach |
| title_full | Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach |
| title_fullStr | Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach |
| title_full_unstemmed | Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach |
| title_short | Revisiting the Reaction Between Diaminomaleonitrile and Aromatic Aldehydes: a Green Chemistry Approach |
| title_sort | revisiting the reaction between diaminomaleonitrile and aromatic aldehydes a green chemistry approach |
| topic | DAMN monoimines Green Chemistry aromatic aldehydes. |
| url | http://www.mdpi.com/1420-3049/11/11/858/ |
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