(2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II)
The title mononuclear CuII complex, [Cu(C8H5O3)2(C10H8N2)], is comprised of a CuII cation, two 4-formylbenzoate (L−) ligands and a 2,2′-bipyridine (bipy) ligand. The CuII ion and bipy ligand lie on a crystallographic twofold rotation axis; the CuII ion is coordinated by t...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812031066 |
| _version_ | 1818975516915400704 |
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| author | Jin-li Qi Wei Xu |
| author_facet | Jin-li Qi Wei Xu |
| author_sort | Jin-li Qi |
| collection | DOAJ |
| description | The title mononuclear CuII complex, [Cu(C8H5O3)2(C10H8N2)], is comprised of a CuII cation, two 4-formylbenzoate (L−) ligands and a 2,2′-bipyridine (bipy) ligand. The CuII ion and bipy ligand lie on a crystallographic twofold rotation axis; the CuII ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxylate groups of two L− ligands, exhibiting effectively a distorted square-planar geometry. The complex molecules are interlinked to generate two-dimensional supramolecular layers in the ab plane, formed by C—H...O hydrogen bonds, where the O acceptor is the O atom from the carboxylate group not involved in coordination to the CuII ion. The two-dimensional layers are stacked in a sequence via C—H...O hydrogen-bonding interactions where the formyl O atom acts as acceptor. |
| first_indexed | 2024-12-20T15:57:12Z |
| format | Article |
| id | doaj.art-275e662df3de4eb983024c2207631454 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:57:12Z |
| publishDate | 2012-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-275e662df3de4eb983024c22076314542022-12-21T19:34:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688m1062m106310.1107/S1600536812031066(2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II)Jin-li QiWei XuThe title mononuclear CuII complex, [Cu(C8H5O3)2(C10H8N2)], is comprised of a CuII cation, two 4-formylbenzoate (L−) ligands and a 2,2′-bipyridine (bipy) ligand. The CuII ion and bipy ligand lie on a crystallographic twofold rotation axis; the CuII ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxylate groups of two L− ligands, exhibiting effectively a distorted square-planar geometry. The complex molecules are interlinked to generate two-dimensional supramolecular layers in the ab plane, formed by C—H...O hydrogen bonds, where the O acceptor is the O atom from the carboxylate group not involved in coordination to the CuII ion. The two-dimensional layers are stacked in a sequence via C—H...O hydrogen-bonding interactions where the formyl O atom acts as acceptor.http://scripts.iucr.org/cgi-bin/paper?S1600536812031066 |
| spellingShingle | Jin-li Qi Wei Xu (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) Acta Crystallographica Section E |
| title | (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) |
| title_full | (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) |
| title_fullStr | (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) |
| title_full_unstemmed | (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) |
| title_short | (2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II) |
| title_sort | 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 bis 4 formylbenzoato amp 954 o1 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812031066 |
| work_keys_str_mv | AT jinliqi 22amp8242bipyridineamp9542nnamp8242bis4formylbenzoatoamp954o1copperii AT weixu 22amp8242bipyridineamp9542nnamp8242bis4formylbenzoatoamp954o1copperii |