Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3
The Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems were studied in the subsolidus region using X-ray powder diffraction and differential scanning calorimetric (DSC) analysis. Quasi-binary joins were revealed, and triangulation was carried out. New ternary molybdates: Tl5RZr(MoO4)6 (5:1:2) and TlRZ...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2017-12-01
|
| Series: | Chimica Techno Acta |
| Subjects: | |
| Online Access: | https://journals.urfu.ru/index.php/chimtech/article/view/2649 |
| _version_ | 1819283154686443520 |
|---|---|
| author | V. G. Grossman B. G. Bazarov Zh. G. Bazarova |
| author_facet | V. G. Grossman B. G. Bazarov Zh. G. Bazarova |
| author_sort | V. G. Grossman |
| collection | DOAJ |
| description | The Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems were studied in the subsolidus region using X-ray powder diffraction and differential scanning calorimetric (DSC) analysis. Quasi-binary joins were revealed, and triangulation was carried out. New ternary molybdates: Tl5RZr(MoO4)6 (5:1:2) and TlRZr0.5(MoO4)3 (1:1:1) (R = Al, Cr) were prepared. The unit cell parameters for the new compounds were calculated. |
| first_indexed | 2024-12-24T01:26:58Z |
| format | Article |
| id | doaj.art-27684a75343047438e5e29fcbd95ff3f |
| institution | Directory Open Access Journal |
| issn | 2409-5613 2411-1414 |
| language | English |
| last_indexed | 2024-12-24T01:26:58Z |
| publishDate | 2017-12-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj.art-27684a75343047438e5e29fcbd95ff3f2022-12-21T17:22:28ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2409-56132411-14142017-12-014421822310.15826/chimtech/2017.4.4.022354Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3V. G. Grossman0B. G. Bazarov1Zh. G. Bazarova2Baikal Institute of Nature Management SB RAS, Ulan-UdeBaikal Institute of Nature Management SB RAS, Buryat State University, Ulan-UdeBaikal Institute of Nature Management SB RAS, Buryat State University, Ulan-UdeThe Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems were studied in the subsolidus region using X-ray powder diffraction and differential scanning calorimetric (DSC) analysis. Quasi-binary joins were revealed, and triangulation was carried out. New ternary molybdates: Tl5RZr(MoO4)6 (5:1:2) and TlRZr0.5(MoO4)3 (1:1:1) (R = Al, Cr) were prepared. The unit cell parameters for the new compounds were calculated.https://journals.urfu.ru/index.php/chimtech/article/view/2649phase equilibriasynthesisoxide systemsthalliumzirconiumironaluminumcrystal structurespace group |
| spellingShingle | V. G. Grossman B. G. Bazarov Zh. G. Bazarova Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 Chimica Techno Acta phase equilibria synthesis oxide systems thallium zirconium iron aluminum crystal structure space group |
| title | Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 |
| title_full | Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 |
| title_fullStr | Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 |
| title_full_unstemmed | Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 |
| title_short | Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 |
| title_sort | phase equilibria in the tl2moo4 r2 moo4 3 zr moo4 2 r al cr systems synthesis structure and properties of new triple molybdates tl5rzr moo4 6 and tlrzr0 5 moo4 3 |
| topic | phase equilibria synthesis oxide systems thallium zirconium iron aluminum crystal structure space group |
| url | https://journals.urfu.ru/index.php/chimtech/article/view/2649 |
| work_keys_str_mv | AT vggrossman phaseequilibriainthetl2moo4r2moo43zrmoo42ralcrsystemssynthesisstructureandpropertiesofnewtriplemolybdatestl5rzrmoo46andtlrzr05moo43 AT bgbazarov phaseequilibriainthetl2moo4r2moo43zrmoo42ralcrsystemssynthesisstructureandpropertiesofnewtriplemolybdatestl5rzrmoo46andtlrzr05moo43 AT zhgbazarova phaseequilibriainthetl2moo4r2moo43zrmoo42ralcrsystemssynthesisstructureandpropertiesofnewtriplemolybdatestl5rzrmoo46andtlrzr05moo43 |