Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3

Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3

The Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems were studied in the subsolidus region using X-ray powder diffraction and differential scanning calorimetric (DSC) analysis. Quasi-binary joins were revealed, and triangulation was carried out. New ternary molybdates: Tl5RZr(MoO4)6 (5:1:2) and TlRZ...

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Bibliographic Details
Main Authors: V. G. Grossman, B. G. Bazarov, Zh. G. Bazarova
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2017-12-01
Series:Chimica Techno Acta
Subjects:
phase equilibria
synthesis
oxide systems
thallium
zirconium
iron
aluminum
crystal structure
space group
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/2649

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