Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline)
Two complexes of [Mn(Quin)2(N(CN)2)2]∞ (1) and [Co(Quin)2(N(CN)2)2]∞ (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) Å, b = 7.7729(16) Å, c = 9.5968(15) Å, α = 96.388(...
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ITB Journal Publisher
2023-03-01
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| Series: | Journal of Mathematical and Fundamental Sciences |
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| Online Access: | https://journals.itb.ac.id/index.php/jmfs/article/view/18930 |
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| author | I Wayan Dasna Ubed Sonai Fahruddin Arrozi Husni Wahyu Wijaya Sutandyo Dwija Laksmana Stéphane Golhen |
| author_facet | I Wayan Dasna Ubed Sonai Fahruddin Arrozi Husni Wahyu Wijaya Sutandyo Dwija Laksmana Stéphane Golhen |
| author_sort | I Wayan Dasna |
| collection | DOAJ |
| description |
Two complexes of [Mn(Quin)2(N(CN)2)2]∞ (1) and [Co(Quin)2(N(CN)2)2]∞ (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) Å, b = 7.7729(16) Å, c = 9.5968(15) Å, α = 96.388(6) o, β = 112.617(5) o, γ = 102.751(6) o, while for complex 2 it was a = 7.3942(10) Å, b = 7.7960(10) Å, c = 9.4907(13) Å, α = 96.631(4) o, β = 112.742(4) o, γ = 102.458(4) o. The magnetic properties and antimicrobial properties of both polymeric complexes were examined by magnetic susceptibility and diffusion techniques, respectively. Complexes 1 and 2 both showed antiferromagnetic properties and had a higher inhibitory effect on the growth of Staphylococcus aureus than Salmonella typhi.
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| first_indexed | 2024-04-09T21:01:37Z |
| format | Article |
| id | doaj.art-276e9c1e5dcd4cc785c4074a048068b2 |
| institution | Directory Open Access Journal |
| issn | 2337-5760 2338-5510 |
| language | English |
| last_indexed | 2024-04-09T21:01:37Z |
| publishDate | 2023-03-01 |
| publisher | ITB Journal Publisher |
| record_format | Article |
| series | Journal of Mathematical and Fundamental Sciences |
| spelling | doaj.art-276e9c1e5dcd4cc785c4074a048068b22023-03-29T07:39:03ZengITB Journal PublisherJournal of Mathematical and Fundamental Sciences2337-57602338-55102023-03-0154210.5614/j.math.fund.sci.2022.54.2.4Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline)I Wayan Dasna0Ubed Sonai Fahruddin Arrozi1Husni Wahyu Wijaya2Sutandyo Dwija Laksmana3Stéphane Golhen4Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145 Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145 Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145 Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145 University of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, 35000 Rennes, France Two complexes of [Mn(Quin)2(N(CN)2)2]∞ (1) and [Co(Quin)2(N(CN)2)2]∞ (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) Å, b = 7.7729(16) Å, c = 9.5968(15) Å, α = 96.388(6) o, β = 112.617(5) o, γ = 102.751(6) o, while for complex 2 it was a = 7.3942(10) Å, b = 7.7960(10) Å, c = 9.4907(13) Å, α = 96.631(4) o, β = 112.742(4) o, γ = 102.458(4) o. The magnetic properties and antimicrobial properties of both polymeric complexes were examined by magnetic susceptibility and diffusion techniques, respectively. Complexes 1 and 2 both showed antiferromagnetic properties and had a higher inhibitory effect on the growth of Staphylococcus aureus than Salmonella typhi. https://journals.itb.ac.id/index.php/jmfs/article/view/18930Manganese(II) complexCobalt(II) complexquinoline ligandantiferromagneticantibacterial |
| spellingShingle | I Wayan Dasna Ubed Sonai Fahruddin Arrozi Husni Wahyu Wijaya Sutandyo Dwija Laksmana Stéphane Golhen Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) Journal of Mathematical and Fundamental Sciences Manganese(II) complex Cobalt(II) complex quinoline ligand antiferromagnetic antibacterial |
| title | Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) |
| title_full | Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) |
| title_fullStr | Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) |
| title_full_unstemmed | Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) |
| title_short | Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline) |
| title_sort | synthesis structure magnetic and antibacterial properties of polymeric m quin 2 n cn 2 2 ∞ m mn ii co ii quin quinoline |
| topic | Manganese(II) complex Cobalt(II) complex quinoline ligand antiferromagnetic antibacterial |
| url | https://journals.itb.ac.id/index.php/jmfs/article/view/18930 |
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