μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
In the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810045393 |
| _version_ | 1819279933770301440 |
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| author | Amalija Golobič Boris Čeh |
| author_facet | Amalija Golobič Boris Čeh |
| author_sort | Amalija Golobič |
| collection | DOAJ |
| description | In the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the MoV atom via an N2O donor set. The water molecule bridges two complex molecules, forming O—H...O and O—H...Cl hydrogen bonds to the acetate group and to the chloride ligands. |
| first_indexed | 2024-12-24T00:35:47Z |
| format | Article |
| id | doaj.art-2771415f58c3483f934dd939fa8dddda |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:47Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2771415f58c3483f934dd939fa8dddda2022-12-21T17:24:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1648m164910.1107/S1600536810045393μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrateAmalija GolobičBoris ČehIn the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the MoV atom via an N2O donor set. The water molecule bridges two complex molecules, forming O—H...O and O—H...Cl hydrogen bonds to the acetate group and to the chloride ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536810045393 |
| spellingShingle | Amalija Golobič Boris Čeh μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate Acta Crystallographica Section E |
| title | μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate |
| title_full | μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate |
| title_fullStr | μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate |
| title_full_unstemmed | μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate |
| title_short | μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate |
| title_sort | amp 956 oxido bis 2 2 bis 3 5 dimethyl 1h pyrazol 1 yl acetato amp 954 3n2 o n2 amp 8242 chloridooxidomolybdenum v monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810045393 |
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