Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro

In this work, hydrotalcite, a layered double hydroxide, had its adsorption and ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe. The removal of As(V) by a HT-Fe adsorbent was evaluated under various conditions. The Kinetic process was...

Full description

Bibliographic Details
Main Authors: Thiago Vinícius Toledo, Carlos Roberto Bellato, Rafael Henrique do Rosário, José de Oliveira Marques Neto
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2011-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000400002&lng=en&tlng=en
_version_ 1818144969657942016
author Thiago Vinícius Toledo
Carlos Roberto Bellato
Rafael Henrique do Rosário
José de Oliveira Marques Neto
author_facet Thiago Vinícius Toledo
Carlos Roberto Bellato
Rafael Henrique do Rosário
José de Oliveira Marques Neto
author_sort Thiago Vinícius Toledo
collection DOAJ
description In this work, hydrotalcite, a layered double hydroxide, had its adsorption and ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe. The removal of As(V) by a HT-Fe adsorbent was evaluated under various conditions. The Kinetic process was well described by a pseudo-second order rate model. The maximum adsorption capacity, calculated with the Langmuir model showed to be dependent on pH, reaching values of 24.09, 10.19 and 7.44 mg g-1, respectively, for pH values of 4.0, 7.0 and 9.0. The inhibition by competition of anions is dependent on the type of ionic species.
first_indexed 2024-12-11T11:56:01Z
format Article
id doaj.art-279c3efe57694de0b610fe6f310e7a70
institution Directory Open Access Journal
issn 1678-7064
language English
last_indexed 2024-12-11T11:56:01Z
publishDate 2011-01-01
publisher Sociedade Brasileira de Química
record_format Article
series Química Nova
spelling doaj.art-279c3efe57694de0b610fe6f310e7a702022-12-22T01:08:13ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642011-01-0134456156710.1590/S0100-40422011000400002S0100-40422011000400002Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferroThiago Vinícius Toledo0Carlos Roberto Bellato1Rafael Henrique do Rosário2José de Oliveira Marques Neto3Universidade Federal de ViçosaUniversidade Federal de ViçosaUniversidade Federal de ViçosaUniversidade Federal de ViçosaIn this work, hydrotalcite, a layered double hydroxide, had its adsorption and ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe. The removal of As(V) by a HT-Fe adsorbent was evaluated under various conditions. The Kinetic process was well described by a pseudo-second order rate model. The maximum adsorption capacity, calculated with the Langmuir model showed to be dependent on pH, reaching values of 24.09, 10.19 and 7.44 mg g-1, respectively, for pH values of 4.0, 7.0 and 9.0. The inhibition by competition of anions is dependent on the type of ionic species.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000400002&lng=en&tlng=enhidrotalcite - iron oxide compositearsenateadsorption
spellingShingle Thiago Vinícius Toledo
Carlos Roberto Bellato
Rafael Henrique do Rosário
José de Oliveira Marques Neto
Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
Química Nova
hidrotalcite - iron oxide composite
arsenate
adsorption
title Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
title_full Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
title_fullStr Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
title_full_unstemmed Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
title_short Adsorção de arsênio(V) pelo compósito magnético hidrotalcita: óxido de ferro
title_sort adsorcao de arsenio v pelo composito magnetico hidrotalcita oxido de ferro
topic hidrotalcite - iron oxide composite
arsenate
adsorption
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000400002&lng=en&tlng=en
work_keys_str_mv AT thiagoviniciustoledo adsorcaodearseniovpelocompositomagneticohidrotalcitaoxidodeferro
AT carlosrobertobellato adsorcaodearseniovpelocompositomagneticohidrotalcitaoxidodeferro
AT rafaelhenriquedorosario adsorcaodearseniovpelocompositomagneticohidrotalcitaoxidodeferro
AT josedeoliveiramarquesneto adsorcaodearseniovpelocompositomagneticohidrotalcitaoxidodeferro