DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS
Preparation methods of granulated and monolithic Fe-Mn catalysts on the base of ferromanganese nodules were developed. The textural, structural and strength properties of catalysts were studied. It was shown that the catalysts have a developed pore structure and high mechanical strength. The catalys...
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| Format: | Article |
| Language: | English |
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Kemerovo State University
2015-11-01
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| Series: | Вестник Кемеровского государственного университета |
| Subjects: | |
| Online Access: | https://vestnik.kemsu.ru/jour/article/view/307 |
| _version_ | 1827902028820512768 |
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| author | N. V. Shikina S. R. Khairulin S. A. Yashnik A. A. Gavrilovа Z. R. Ismagilov |
| author_facet | N. V. Shikina S. R. Khairulin S. A. Yashnik A. A. Gavrilovа Z. R. Ismagilov |
| author_sort | N. V. Shikina |
| collection | DOAJ |
| description | Preparation methods of granulated and monolithic Fe-Mn catalysts on the base of ferromanganese nodules were developed. The textural, structural and strength properties of catalysts were studied. It was shown that the catalysts have a developed pore structure and high mechanical strength. The catalysts were tested in the DeSOx reaction with synthesis gas at a stoichiometric ratio SO2/(CО+H2)=0,5. The effect of the preliminary catalysts sulfidizing and geometric shape of samples (granules and monolith) on the catalytic properties were investigated. The testing showed that Fe-Mn catalysts with the oxide or sulfide form of active components are active in DeSOx reaction with synthesis gas and can selectively reduce SO2 with a conversion above 90 %. |
| first_indexed | 2024-03-12T23:53:57Z |
| format | Article |
| id | doaj.art-27ac13562697425ba37a7b56211192fe |
| institution | Directory Open Access Journal |
| issn | 2078-8975 2078-8983 |
| language | English |
| last_indexed | 2024-03-12T23:53:57Z |
| publishDate | 2015-11-01 |
| publisher | Kemerovo State University |
| record_format | Article |
| series | Вестник Кемеровского государственного университета |
| spelling | doaj.art-27ac13562697425ba37a7b56211192fe2023-07-13T12:08:43ZengKemerovo State UniversityВестник Кемеровского государственного университета2078-89752078-89832015-11-0104-3252258307DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTSN. V. Shikina0S. R. Khairulin1S. A. Yashnik2A. A. Gavrilovа3Z. R. Ismagilov4Boreskov Institute of Catalysis of SBRAS, NovosibirskBoreskov Institute of Catalysis of SBRAS, NovosibirskBoreskov Institute of Catalysis of SBRAS, NovosibirskBoreskov Institute of Catalysis of SBRAS, NovosibirskInstitute of Coal Chemistry and Material Science of SB RASPreparation methods of granulated and monolithic Fe-Mn catalysts on the base of ferromanganese nodules were developed. The textural, structural and strength properties of catalysts were studied. It was shown that the catalysts have a developed pore structure and high mechanical strength. The catalysts were tested in the DeSOx reaction with synthesis gas at a stoichiometric ratio SO2/(CО+H2)=0,5. The effect of the preliminary catalysts sulfidizing and geometric shape of samples (granules and monolith) on the catalytic properties were investigated. The testing showed that Fe-Mn catalysts with the oxide or sulfide form of active components are active in DeSOx reaction with synthesis gas and can selectively reduce SO2 with a conversion above 90 %.https://vestnik.kemsu.ru/jour/article/view/307catalysts, monoliths, preparation, desox, synthesis gas |
| spellingShingle | N. V. Shikina S. R. Khairulin S. A. Yashnik A. A. Gavrilovа Z. R. Ismagilov DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS Вестник Кемеровского государственного университета catalysts, monoliths, preparation, desox, synthesis gas |
| title | DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS |
| title_full | DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS |
| title_fullStr | DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS |
| title_full_unstemmed | DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS |
| title_short | DIRECT CATALYTIC REDUCTION OF SO2BY SYNTHESIS GASOVER GRANULATED AND MONOLITHIC Fe-Mn CATALYSTS |
| title_sort | direct catalytic reduction of so2by synthesis gasover granulated and monolithic fe mn catalysts |
| topic | catalysts, monoliths, preparation, desox, synthesis gas |
| url | https://vestnik.kemsu.ru/jour/article/view/307 |
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