Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water
A green procedure is described for supporting Pd nanoparticles on hydroxyapatite (HAP), which serves as a highly-stable heterogeneous catalyst displaying excellent activity for the aqueous expeditious reduction of nitroaromatics to the corresponding amines with sodium borohydride, and oxidation of p...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-10-01
|
| Series: | Applied Sciences |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2076-3417/9/19/4183 |
| _version_ | 1818900152160616448 |
|---|---|
| author | Mohammadreza Shokouhimehr Samaneh Mahmoudi-Gom Yek Mahmoud Nasrollahzadeh Aejung Kim Rajender S. Varma |
| author_facet | Mohammadreza Shokouhimehr Samaneh Mahmoudi-Gom Yek Mahmoud Nasrollahzadeh Aejung Kim Rajender S. Varma |
| author_sort | Mohammadreza Shokouhimehr |
| collection | DOAJ |
| description | A green procedure is described for supporting Pd nanoparticles on hydroxyapatite (HAP), which serves as a highly-stable heterogeneous catalyst displaying excellent activity for the aqueous expeditious reduction of nitroaromatics to the corresponding amines with sodium borohydride, and oxidation of primary and secondary alcohols by hydrogen peroxide with high yields and selectivities. The structural features of the prepared catalyst are confirmed by latest techniques including field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The reusability of the heterogeneous catalyst was affirmed in the aqueous reduction of nitrobenzene and oxidation of cycloheptanol for six consecutive runs without significant loss of catalytic activity. |
| first_indexed | 2024-12-19T19:59:19Z |
| format | Article |
| id | doaj.art-27f565a22c1148c8b353f919e52995e5 |
| institution | Directory Open Access Journal |
| issn | 2076-3417 |
| language | English |
| last_indexed | 2024-12-19T19:59:19Z |
| publishDate | 2019-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Applied Sciences |
| spelling | doaj.art-27f565a22c1148c8b353f919e52995e52022-12-21T20:07:43ZengMDPI AGApplied Sciences2076-34172019-10-01919418310.3390/app9194183app9194183Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in WaterMohammadreza Shokouhimehr0Samaneh Mahmoudi-Gom Yek1Mahmoud Nasrollahzadeh2Aejung Kim3Rajender S. Varma4Department of Material Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 08826, KoreaDepartment of Chemistry, Bu-Ali Sina University, Hamedan 65178, IranDepartment of Chemistry, Faculty of Science, University of Qom, Qom 3716146611, IranAsia Center, Seoul National University, Seoul 08826, KoreaRegional Center of Advanced Technologies and Materials, Department of Physical Chemistry, Faculty of Science, Palacky University, Šlechtitelů 27, 783 71 Olomouc, Czech RepublicA green procedure is described for supporting Pd nanoparticles on hydroxyapatite (HAP), which serves as a highly-stable heterogeneous catalyst displaying excellent activity for the aqueous expeditious reduction of nitroaromatics to the corresponding amines with sodium borohydride, and oxidation of primary and secondary alcohols by hydrogen peroxide with high yields and selectivities. The structural features of the prepared catalyst are confirmed by latest techniques including field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The reusability of the heterogeneous catalyst was affirmed in the aqueous reduction of nitrobenzene and oxidation of cycloheptanol for six consecutive runs without significant loss of catalytic activity.https://www.mdpi.com/2076-3417/9/19/4183hydroxyapatitepalladium nanocatalystsheterogeneous catalysisoxidationreductionalcoholnitrobenzene |
| spellingShingle | Mohammadreza Shokouhimehr Samaneh Mahmoudi-Gom Yek Mahmoud Nasrollahzadeh Aejung Kim Rajender S. Varma Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water Applied Sciences hydroxyapatite palladium nanocatalysts heterogeneous catalysis oxidation reduction alcohol nitrobenzene |
| title | Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water |
| title_full | Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water |
| title_fullStr | Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water |
| title_full_unstemmed | Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water |
| title_short | Palladium Nanocatalysts on Hydroxyapatite: Green Oxidation of Alcohols and Reduction of Nitroarenes in Water |
| title_sort | palladium nanocatalysts on hydroxyapatite green oxidation of alcohols and reduction of nitroarenes in water |
| topic | hydroxyapatite palladium nanocatalysts heterogeneous catalysis oxidation reduction alcohol nitrobenzene |
| url | https://www.mdpi.com/2076-3417/9/19/4183 |
| work_keys_str_mv | AT mohammadrezashokouhimehr palladiumnanocatalystsonhydroxyapatitegreenoxidationofalcoholsandreductionofnitroarenesinwater AT samanehmahmoudigomyek palladiumnanocatalystsonhydroxyapatitegreenoxidationofalcoholsandreductionofnitroarenesinwater AT mahmoudnasrollahzadeh palladiumnanocatalystsonhydroxyapatitegreenoxidationofalcoholsandreductionofnitroarenesinwater AT aejungkim palladiumnanocatalystsonhydroxyapatitegreenoxidationofalcoholsandreductionofnitroarenesinwater AT rajendersvarma palladiumnanocatalystsonhydroxyapatitegreenoxidationofalcoholsandreductionofnitroarenesinwater |