Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles.
In this study, we investigated different metal pairings of Au nanoparticles (NPs) as potential catalysts for glycerol dehydration for the first time. All of the systems preferred the formation of hydroxyacetone (HYNE). Although the bimetallics that were tested, i.e., Au NPs supported on Ni, Fe and C...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Public Library of Science (PLoS)
2015-01-01
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| Series: | PLoS ONE |
| Online Access: | http://europepmc.org/articles/PMC4651318?pdf=render |
| _version_ | 1818994690346713088 |
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| author | Maciej Kapkowski Tomasz Siudyga Rafal Sitko Józef Lelątko Jacek Szade Katarzyna Balin Joanna Klimontko Piotr Bartczak Jaroslaw Polanski |
| author_facet | Maciej Kapkowski Tomasz Siudyga Rafal Sitko Józef Lelątko Jacek Szade Katarzyna Balin Joanna Klimontko Piotr Bartczak Jaroslaw Polanski |
| author_sort | Maciej Kapkowski |
| collection | DOAJ |
| description | In this study, we investigated different metal pairings of Au nanoparticles (NPs) as potential catalysts for glycerol dehydration for the first time. All of the systems preferred the formation of hydroxyacetone (HYNE). Although the bimetallics that were tested, i.e., Au NPs supported on Ni, Fe and Cu appeared to be more active than the Au/SiO2 system, only Cu supported Au NPs gave high conversion (ca. 63%) and selectivity (ca. 70%) to HYNE. |
| first_indexed | 2024-12-20T21:01:57Z |
| format | Article |
| id | doaj.art-280793d8eaaf4afdaa621f35f4b090c5 |
| institution | Directory Open Access Journal |
| issn | 1932-6203 |
| language | English |
| last_indexed | 2024-12-20T21:01:57Z |
| publishDate | 2015-01-01 |
| publisher | Public Library of Science (PLoS) |
| record_format | Article |
| series | PLoS ONE |
| spelling | doaj.art-280793d8eaaf4afdaa621f35f4b090c52022-12-21T19:26:41ZengPublic Library of Science (PLoS)PLoS ONE1932-62032015-01-011011e014266810.1371/journal.pone.0142668Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles.Maciej KapkowskiTomasz SiudygaRafal SitkoJózef LelątkoJacek SzadeKatarzyna BalinJoanna KlimontkoPiotr BartczakJaroslaw PolanskiIn this study, we investigated different metal pairings of Au nanoparticles (NPs) as potential catalysts for glycerol dehydration for the first time. All of the systems preferred the formation of hydroxyacetone (HYNE). Although the bimetallics that were tested, i.e., Au NPs supported on Ni, Fe and Cu appeared to be more active than the Au/SiO2 system, only Cu supported Au NPs gave high conversion (ca. 63%) and selectivity (ca. 70%) to HYNE.http://europepmc.org/articles/PMC4651318?pdf=render |
| spellingShingle | Maciej Kapkowski Tomasz Siudyga Rafal Sitko Józef Lelątko Jacek Szade Katarzyna Balin Joanna Klimontko Piotr Bartczak Jaroslaw Polanski Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. PLoS ONE |
| title | Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. |
| title_full | Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. |
| title_fullStr | Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. |
| title_full_unstemmed | Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. |
| title_short | Catalytic Gas-Phase Glycerol Processing over SiO2-, Cu-, Ni- and Fe- Supported Au Nanoparticles. |
| title_sort | catalytic gas phase glycerol processing over sio2 cu ni and fe supported au nanoparticles |
| url | http://europepmc.org/articles/PMC4651318?pdf=render |
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