Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products
A novel and efficient sample pretreatment procedure using magnetic particles was exploited for the determination of multi-pesticide residues in aquatic products. The magnetic adsorbent was prepared using divinyl benzene and N-vinyl pyrrolidone as functional monomers modified on the Fe3O4 @SiO2. The...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2022-08-01
|
| Series: | Ecotoxicology and Environmental Safety |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0147651322006704 |
| _version_ | 1811224483407593472 |
|---|---|
| author | Zhenzhen Liu Huiyu Zhao Jiao Wang Zhiwei Wang Shanshan Di Hao Xu Qiang Wang Xinhong Wang Xinquan Wang Peipei Qi |
| author_facet | Zhenzhen Liu Huiyu Zhao Jiao Wang Zhiwei Wang Shanshan Di Hao Xu Qiang Wang Xinhong Wang Xinquan Wang Peipei Qi |
| author_sort | Zhenzhen Liu |
| collection | DOAJ |
| description | A novel and efficient sample pretreatment procedure using magnetic particles was exploited for the determination of multi-pesticide residues in aquatic products. The magnetic adsorbent was prepared using divinyl benzene and N-vinyl pyrrolidone as functional monomers modified on the Fe3O4 @SiO2. The obtained magnetic adsorbent, octadecylsilane sorbents, and graphitized carbon black were employed as effective adsorbents to remove matrix interferences in aquatic products, and their dosages were optimized. Satisfactory levels of accuracy and precision were procured under optimum conditions. The method limits of quantification ranged from 0.1 to 2.0 μg/kg. The analytical accuracy of the developed method for the analysis of multi-pesticide residues in freshwater and seafood products was validated. It was found to be suitable for the analysis of multi-pesticide residues in different types of aquatic products. Additionally, the method was successfully applied for the analysis of pesticide residues in fish samples obtained from aquaculture plants located in Zhejiang Province, China. The detected concentrations of pesticides ranged from 0.14 to 0.95 μg/kg. In general, this method shows promising application prospects for the rapid determination of multi-pesticide residues in aquatic products. |
| first_indexed | 2024-04-12T08:50:16Z |
| format | Article |
| id | doaj.art-282e6ebec532456da63de63abb64c533 |
| institution | Directory Open Access Journal |
| issn | 0147-6513 |
| language | English |
| last_indexed | 2024-04-12T08:50:16Z |
| publishDate | 2022-08-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Ecotoxicology and Environmental Safety |
| spelling | doaj.art-282e6ebec532456da63de63abb64c5332022-12-22T03:39:36ZengElsevierEcotoxicology and Environmental Safety0147-65132022-08-01241113830Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic productsZhenzhen Liu0Huiyu Zhao1Jiao Wang2Zhiwei Wang3Shanshan Di4Hao Xu5Qiang Wang6Xinhong Wang7Xinquan Wang8Peipei Qi9State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Xiamen University, Xiamen 361005, ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR ChinaState Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Xiamen University, Xiamen 361005, China; Corresponding author.State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR China; Corresponding authors at: State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China.State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China; Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Hangzhou 310021, PR China; Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Hangzhou 310021, PR China; Corresponding authors at: State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, PR China.A novel and efficient sample pretreatment procedure using magnetic particles was exploited for the determination of multi-pesticide residues in aquatic products. The magnetic adsorbent was prepared using divinyl benzene and N-vinyl pyrrolidone as functional monomers modified on the Fe3O4 @SiO2. The obtained magnetic adsorbent, octadecylsilane sorbents, and graphitized carbon black were employed as effective adsorbents to remove matrix interferences in aquatic products, and their dosages were optimized. Satisfactory levels of accuracy and precision were procured under optimum conditions. The method limits of quantification ranged from 0.1 to 2.0 μg/kg. The analytical accuracy of the developed method for the analysis of multi-pesticide residues in freshwater and seafood products was validated. It was found to be suitable for the analysis of multi-pesticide residues in different types of aquatic products. Additionally, the method was successfully applied for the analysis of pesticide residues in fish samples obtained from aquaculture plants located in Zhejiang Province, China. The detected concentrations of pesticides ranged from 0.14 to 0.95 μg/kg. In general, this method shows promising application prospects for the rapid determination of multi-pesticide residues in aquatic products.http://www.sciencedirect.com/science/article/pii/S0147651322006704Magnetic particlesMulti-pesticide residuesAquatic productsLiquid chromatography-tandem mass spectrometry |
| spellingShingle | Zhenzhen Liu Huiyu Zhao Jiao Wang Zhiwei Wang Shanshan Di Hao Xu Qiang Wang Xinhong Wang Xinquan Wang Peipei Qi Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products Ecotoxicology and Environmental Safety Magnetic particles Multi-pesticide residues Aquatic products Liquid chromatography-tandem mass spectrometry |
| title | Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products |
| title_full | Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products |
| title_fullStr | Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products |
| title_full_unstemmed | Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products |
| title_short | Magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi-pesticide residues analysis in aquatic products |
| title_sort | magnetic polymer particles as a highly efficient and facile cleanup adsorbent for multi pesticide residues analysis in aquatic products |
| topic | Magnetic particles Multi-pesticide residues Aquatic products Liquid chromatography-tandem mass spectrometry |
| url | http://www.sciencedirect.com/science/article/pii/S0147651322006704 |
| work_keys_str_mv | AT zhenzhenliu magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT huiyuzhao magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT jiaowang magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT zhiweiwang magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT shanshandi magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT haoxu magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT qiangwang magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT xinhongwang magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT xinquanwang magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts AT peipeiqi magneticpolymerparticlesasahighlyefficientandfacilecleanupadsorbentformultipesticideresiduesanalysisinaquaticproducts |