Short-Time Events, Coherence, and Structural Dynamics in Photochemistry of Aqueous Halogenated Transition Metal Dianions

Short-Time Events, Coherence, and Structural Dynamics in Photochemistry of Aqueous Halogenated Transition Metal Dianions

Ultrafast pump-probe spectroscopy, time-resolved x-ray absorption, and computational photochemistry elucidate the photochemical pathway of hexabromoplatinate dianions that propagates through distortions of nascent penta-bromoplatinate anions caused by Jahn-Teller conical intersections and terminates...

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Main Authors: Pascher T., Uhlig J., Butaeva E.V., Ryazantsev M.N., Mereshchenko A.S., Pal S.K., El-Khoury P. Z., Zheldakov I.L., Tarnovsky A.N., Milne C.J., Johnson S.L.
Format: Article
Language:English
Published: EDP Sciences 2013-03-01
Series:EPJ Web of Conferences
Online Access:http://dx.doi.org/10.1051/epjconf/20134105038

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