Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process

Acetaminophen (C<sub>8</sub>H<sub>9</sub>NO<sub>2</sub>, also called paracetamol) is an active metabolite of phenacetin with antipyretic and analgesic effects and has been extensively used as a painkiller. Currently, the problem of pharmaceuticals in water and sew...

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Main Authors: Agata Skwarczynska-Wojsa, Alicja Puszkarewicz
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/2/431
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author Agata Skwarczynska-Wojsa
Alicja Puszkarewicz
author_facet Agata Skwarczynska-Wojsa
Alicja Puszkarewicz
author_sort Agata Skwarczynska-Wojsa
collection DOAJ
description Acetaminophen (C<sub>8</sub>H<sub>9</sub>NO<sub>2</sub>, also called paracetamol) is an active metabolite of phenacetin with antipyretic and analgesic effects and has been extensively used as a painkiller. Currently, the problem of pharmaceuticals in water and sewage is common, especially in highly urbanized countries. Laboratory-scale experiments were carried out using an adsorbent—granulated activated carbon (WD-extra)—to remove acetaminophen (ACT) from water. The initial concentration of acetaminophen was 20 mg ACT/dm<sup>3</sup>. The adsorption kinetics, influence of the pH on adsorption and dose of the used adsorbent were determined under batch conditions. The adsorption of ACT on activated carbon was more efficient when the water solution was acidic (at pH 2, it was the most effective). The highest percentage of removal (99%) was obtained for the WD-extra dose of 10.0 g/dm<sup>3</sup>. The time taken to establish the dynamic equilibrium of the system was 60 min. The effectiveness of adsorption was determined based on the Freundlich and Langmuir adsorption isotherms. It was found that WD-extra activated carbon effectively removed ACT from water solutions.
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spelling doaj.art-285668bbb3904632a3ad05208c43b4a02024-01-26T17:28:43ZengMDPI AGMaterials1996-19442024-01-0117243110.3390/ma17020431Removal of Acetaminophen from Aqueous Solutions in an Adsorption ProcessAgata Skwarczynska-Wojsa0Alicja Puszkarewicz1Department of Water Purification and Protection, Rzeszow University of Technology, Al. Powstancow Warszawy 12, 35-959 Rzeszow, PolandDepartment of Water Purification and Protection, Rzeszow University of Technology, Al. Powstancow Warszawy 12, 35-959 Rzeszow, PolandAcetaminophen (C<sub>8</sub>H<sub>9</sub>NO<sub>2</sub>, also called paracetamol) is an active metabolite of phenacetin with antipyretic and analgesic effects and has been extensively used as a painkiller. Currently, the problem of pharmaceuticals in water and sewage is common, especially in highly urbanized countries. Laboratory-scale experiments were carried out using an adsorbent—granulated activated carbon (WD-extra)—to remove acetaminophen (ACT) from water. The initial concentration of acetaminophen was 20 mg ACT/dm<sup>3</sup>. The adsorption kinetics, influence of the pH on adsorption and dose of the used adsorbent were determined under batch conditions. The adsorption of ACT on activated carbon was more efficient when the water solution was acidic (at pH 2, it was the most effective). The highest percentage of removal (99%) was obtained for the WD-extra dose of 10.0 g/dm<sup>3</sup>. The time taken to establish the dynamic equilibrium of the system was 60 min. The effectiveness of adsorption was determined based on the Freundlich and Langmuir adsorption isotherms. It was found that WD-extra activated carbon effectively removed ACT from water solutions.https://www.mdpi.com/1996-1944/17/2/431adsorptionactivated carbonacetaminophenparacetamolkineticsequilibrium
spellingShingle Agata Skwarczynska-Wojsa
Alicja Puszkarewicz
Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
Materials
adsorption
activated carbon
acetaminophen
paracetamol
kinetics
equilibrium
title Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
title_full Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
title_fullStr Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
title_full_unstemmed Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
title_short Removal of Acetaminophen from Aqueous Solutions in an Adsorption Process
title_sort removal of acetaminophen from aqueous solutions in an adsorption process
topic adsorption
activated carbon
acetaminophen
paracetamol
kinetics
equilibrium
url https://www.mdpi.com/1996-1944/17/2/431
work_keys_str_mv AT agataskwarczynskawojsa removalofacetaminophenfromaqueoussolutionsinanadsorptionprocess
AT alicjapuszkarewicz removalofacetaminophenfromaqueoussolutionsinanadsorptionprocess