Recent advances in polyoxometalate-based lanthanide–oxo clusters
Polyoxometalate (POM)-based lanthanide-oxo clusters (LnOCs) are a class of polynuclear lanthanide–oxygen complexes formed by polyoxometalate stabilization through oxygen bridges in which POMs can be viewed as multidentate inorganic ligands. POM-based LnOCs have received interest owing to their inter...
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2023-06-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2023.9140022 |
| _version_ | 1797801026948956160 |
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| author | Shu-Rong Li Wei-Dong Liu La-Sheng Long Lan-Sun Zheng Xiang-Jian Kong |
| author_facet | Shu-Rong Li Wei-Dong Liu La-Sheng Long Lan-Sun Zheng Xiang-Jian Kong |
| author_sort | Shu-Rong Li |
| collection | DOAJ |
| description | Polyoxometalate (POM)-based lanthanide-oxo clusters (LnOCs) are a class of polynuclear lanthanide–oxygen complexes formed by polyoxometalate stabilization through oxygen bridges in which POMs can be viewed as multidentate inorganic ligands. POM-based LnOCs have received interest owing to their interesting structures and potential applications. In this paper, we summarize the classification, synthesis strategies, and properties of POM-based LnOCs. POM-based LnOCs are classified into three main categories according to their metal core element type and quantity: pure 4f clusters, 5d–4f clusters, and 3d–4f clusters. Their synthetic strategies are divided into four categories based on the source of the POM involved in the structural assembly: the lacunary POMs ligand-directed method, the in-situ transformation of lacunary POMs ligand-directed method, the in-situ generation of lacunary POMs ligand-directed method, and mixed synthesis strategies. In addition, the single-molecule magnets of POM-based LnOCs and their proton conduction properties are summarized. |
| first_indexed | 2024-03-13T04:44:10Z |
| format | Article |
| id | doaj.art-2869e9c7f2e34a7ba80bae3881f4099e |
| institution | Directory Open Access Journal |
| issn | 2957-9821 2957-9503 |
| language | English |
| last_indexed | 2024-03-13T04:44:10Z |
| publishDate | 2023-06-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Polyoxometalates |
| spelling | doaj.art-2869e9c7f2e34a7ba80bae3881f4099e2023-06-19T03:59:46ZengTsinghua University PressPolyoxometalates2957-98212957-95032023-06-01229140022914002210.26599/POM.2023.9140022Recent advances in polyoxometalate-based lanthanide–oxo clustersShu-Rong Li0Wei-Dong Liu1La-Sheng Long2Lan-Sun Zheng3Xiang-Jian Kong4https://orcid.org/0000-0003-0676-6923Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaCollaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaCollaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaCollaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaCollaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaPolyoxometalate (POM)-based lanthanide-oxo clusters (LnOCs) are a class of polynuclear lanthanide–oxygen complexes formed by polyoxometalate stabilization through oxygen bridges in which POMs can be viewed as multidentate inorganic ligands. POM-based LnOCs have received interest owing to their interesting structures and potential applications. In this paper, we summarize the classification, synthesis strategies, and properties of POM-based LnOCs. POM-based LnOCs are classified into three main categories according to their metal core element type and quantity: pure 4f clusters, 5d–4f clusters, and 3d–4f clusters. Their synthetic strategies are divided into four categories based on the source of the POM involved in the structural assembly: the lacunary POMs ligand-directed method, the in-situ transformation of lacunary POMs ligand-directed method, the in-situ generation of lacunary POMs ligand-directed method, and mixed synthesis strategies. In addition, the single-molecule magnets of POM-based LnOCs and their proton conduction properties are summarized.https://www.sciopen.com/article/10.26599/POM.2023.9140022polyoxometalateslanthanideclusterssynthetic strategyapplications |
| spellingShingle | Shu-Rong Li Wei-Dong Liu La-Sheng Long Lan-Sun Zheng Xiang-Jian Kong Recent advances in polyoxometalate-based lanthanide–oxo clusters Polyoxometalates polyoxometalates lanthanide clusters synthetic strategy applications |
| title | Recent advances in polyoxometalate-based lanthanide–oxo clusters |
| title_full | Recent advances in polyoxometalate-based lanthanide–oxo clusters |
| title_fullStr | Recent advances in polyoxometalate-based lanthanide–oxo clusters |
| title_full_unstemmed | Recent advances in polyoxometalate-based lanthanide–oxo clusters |
| title_short | Recent advances in polyoxometalate-based lanthanide–oxo clusters |
| title_sort | recent advances in polyoxometalate based lanthanide oxo clusters |
| topic | polyoxometalates lanthanide clusters synthetic strategy applications |
| url | https://www.sciopen.com/article/10.26599/POM.2023.9140022 |
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