Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries

For an efficient flow battery operation, knowledge of the state of charge of the battery is essential. Monitoring the state of charge of both half cells is advantageous concerning a timely detection of crossover processes. We present the first results for amperometric and electrochemical quartz cry...

Full description

Bibliographic Details
Main Authors: Claudia Weidlich, Felix Lulay, Matthias Wieland
Format: Article
Language:English
Published: International Association of Physical Chemists (IAPC) 2023-05-01
Series:Journal of Electrochemical Science and Engineering
Subjects:
Online Access:https://pub.iapchem.org/ojs/index.php/JESE/article/view/1699
_version_ 1797797248372834304
author Claudia Weidlich
Felix Lulay
Matthias Wieland
author_facet Claudia Weidlich
Felix Lulay
Matthias Wieland
author_sort Claudia Weidlich
collection DOAJ
description For an efficient flow battery operation, knowledge of the state of charge of the battery is essential. Monitoring the state of charge of both half cells is advantageous concerning a timely detection of crossover processes. We present the first results for amperometric and electrochemical quartz crystal microbalance measurements in a vanadium flow battery test setup. By validating with half cell potential measurements as well as ex situ titration we investigate the applicability of both electrochemical methods for an in situ half cell state of charge monitoring.
first_indexed 2024-03-13T03:46:21Z
format Article
id doaj.art-289a483324f34ce383939067f1e0a57d
institution Directory Open Access Journal
issn 1847-9286
language English
last_indexed 2024-03-13T03:46:21Z
publishDate 2023-05-01
publisher International Association of Physical Chemists (IAPC)
record_format Article
series Journal of Electrochemical Science and Engineering
spelling doaj.art-289a483324f34ce383939067f1e0a57d2023-06-22T21:05:06ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862023-05-0110.5599/jese.1699Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteriesClaudia Weidlich0Felix Lulay1Matthias Wieland2DECHEMA-Forschungsinstitut, Theodor-Heuss-Allee 25, 60486 Frankfurt, GermanyDECHEMA-Forschungsinstitut, Theodor-Heuss-Allee 25, 60486 Frankfurt, Germany and Centre for Electrochemical and Surface Technology, Viktor-Kaplan-Strasse 2, 2700 Wr. Neustadt, AustriaDECHEMA-Forschungsinstitut, Theodor-Heuss-Allee 25, 60486 Frankfurt, Germany For an efficient flow battery operation, knowledge of the state of charge of the battery is essential. Monitoring the state of charge of both half cells is advantageous concerning a timely detection of crossover processes. We present the first results for amperometric and electrochemical quartz crystal microbalance measurements in a vanadium flow battery test setup. By validating with half cell potential measurements as well as ex situ titration we investigate the applicability of both electrochemical methods for an in situ half cell state of charge monitoring. https://pub.iapchem.org/ojs/index.php/JESE/article/view/1699Crossoverhalf-cellelectrolyte properties
spellingShingle Claudia Weidlich
Felix Lulay
Matthias Wieland
Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
Journal of Electrochemical Science and Engineering
Crossover
half-cell
electrolyte properties
title Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
title_full Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
title_fullStr Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
title_full_unstemmed Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
title_short Feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
title_sort feasibility study of amperometric and electrochemical quartz crystal microbalance measurements for in situ state of charge monitoring in vanadium flow batteries
topic Crossover
half-cell
electrolyte properties
url https://pub.iapchem.org/ojs/index.php/JESE/article/view/1699
work_keys_str_mv AT claudiaweidlich feasibilitystudyofamperometricandelectrochemicalquartzcrystalmicrobalancemeasurementsforinsitustateofchargemonitoringinvanadiumflowbatteries
AT felixlulay feasibilitystudyofamperometricandelectrochemicalquartzcrystalmicrobalancemeasurementsforinsitustateofchargemonitoringinvanadiumflowbatteries
AT matthiaswieland feasibilitystudyofamperometricandelectrochemicalquartzcrystalmicrobalancemeasurementsforinsitustateofchargemonitoringinvanadiumflowbatteries